On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Derek H.R. Barton; David Crich; Antonius Löbberding; Samir Z. Zard

doi:10.1039/C39850000646

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Derek H.R. Barton
, David Crich
, Antonius Löbberding
, Samir Z. Zard

Institut de Chimie des Substances Naturelles

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct S_H2 attack on sulphide sulphur.

Original language	English
Pages (from-to)	646-647
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39850000646
Publication status	Published - 1 Jan 1985
Externally published	Yes

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title = "On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane",

abstract = "Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.",

author = "Barton, \{Derek H.R.\} and David Crich and Antonius L{\"o}bberding and Zard, \{Samir Z.\}",

year = "1985",

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doi = "10.1039/C39850000646",

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AU - Barton, Derek H.R.

AU - Crich, David

AU - Löbberding, Antonius

AU - Zard, Samir Z.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.

AB - Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.

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DO - 10.1039/C39850000646

M3 - Article

AN - SCOPUS:24744466816

SN - 0022-4936

SP - 646

EP - 647

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Abstract

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