Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

Jean Philippe Tranchier; René Chavignon; Damien Prim; Audrey Auffrant; Jose Giner Planas; Françoise Rose-Munch; Eric Rose; G. Richard Stephenson

doi:10.1016/S0040-4039(01)00445-2

Organochromium/organoiron dipoles comprising (η⁶-arene)chromium and (η⁵-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

Jean Philippe Tranchier
, René Chavignon
, Damien Prim
, Audrey Auffrant
, Jose Giner Planas
, Françoise Rose-Munch
, Eric Rose
, G. Richard Stephenson

Centre national de la recherche scientifique
University of East Anglia

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

Original language	English
Pages (from-to)	3311-3313
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4039(01)00445-2
Publication status	Published - 7 May 2001

Keywords

Alkyne
Bimetallic dipoles
Nonlinear optics
Thiophene
Tricarbonylarenechromium
Tricarbonylcyclohexadienyliron

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10.1016/S0040-4039(01)00445-2

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title = "Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers",

abstract = "The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.",

keywords = "Alkyne, Bimetallic dipoles, Nonlinear optics, Thiophene, Tricarbonylarenechromium, Tricarbonylcyclohexadienyliron",

author = "Tranchier, \{Jean Philippe\} and Ren{\'e} Chavignon and Damien Prim and Audrey Auffrant and Planas, \{Jose Giner\} and Fran{\c c}oise Rose-Munch and Eric Rose and Stephenson, \{G. Richard\}",

year = "2001",

month = may,

day = "7",

doi = "10.1016/S0040-4039(01)00445-2",

language = "English",

volume = "42",

pages = "3311--3313",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "19",

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TY - JOUR

T1 - Organochromium/organoiron dipoles comprising (η6-arene)chromium and (η5-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

AU - Tranchier, Jean Philippe

AU - Chavignon, René

AU - Prim, Damien

AU - Auffrant, Audrey

AU - Planas, Jose Giner

AU - Rose-Munch, Françoise

AU - Rose, Eric

AU - Stephenson, G. Richard

PY - 2001/5/7

Y1 - 2001/5/7

N2 - The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

AB - The synthesis of novel bimetallic organochromium/organoiron monocation dipoles comprising π-conjugated complexes linked with conjugated spacers has been performed utilising Stille and Sonogashira coupling reactions. This work establishes a general strategy for the synthesis of mixed-metal chromium/dipole complexes for evaluation for nonlinear optical effects by hyper-Rayleigh scattering.

KW - Alkyne

KW - Bimetallic dipoles

KW - Nonlinear optics

KW - Thiophene

KW - Tricarbonylarenechromium

KW - Tricarbonylcyclohexadienyliron

UR - https://www.scopus.com/pages/publications/0035821318

U2 - 10.1016/S0040-4039(01)00445-2

DO - 10.1016/S0040-4039(01)00445-2

M3 - Article

AN - SCOPUS:0035821318

SN - 0040-4039

VL - 42

SP - 3311

EP - 3313

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 19

ER -

Organochromium/organoiron dipoles comprising (η⁶-arene)chromium and (η⁵-cyclohexadienyl)iron(1+) complexes linked with conjugated spacers

Abstract

Keywords

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