Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

Solène Morand; William Lecroq; Philippe Jubault; Sami Lakhdar; Jean Philippe Bouillon; Samuel Couve-Bonnaire

doi:10.1021/acs.orglett.2c03366

Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

Solène Morand
, William Lecroq
, Philippe Jubault
, Sami Lakhdar
, Jean Philippe Bouillon
, Samuel Couve-Bonnaire

Normandie Univ
CNRS
Université Paul Sabatier

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

Original language	English
Pages (from-to)	8343-8347
Number of pages	5
Journal	Organic Letters
Volume	24
Issue number	45
DOIs	https://doi.org/10.1021/acs.orglett.2c03366
Publication status	Published - 18 Nov 2022
Externally published	Yes

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10.1021/acs.orglett.2c03366

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abstract = "gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.",

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T1 - Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

AU - Morand, Solène

AU - Lecroq, William

AU - Jubault, Philippe

AU - Lakhdar, Sami

AU - Bouillon, Jean Philippe

AU - Couve-Bonnaire, Samuel

PY - 2022/11/18

Y1 - 2022/11/18

N2 - gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

AB - gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields, and the reaction showed very good chemical tolerance.

UR - https://www.scopus.com/pages/publications/85141950856

U2 - 10.1021/acs.orglett.2c03366

DO - 10.1021/acs.orglett.2c03366

M3 - Article

C2 - 36350256

AN - SCOPUS:85141950856

SN - 1523-7060

VL - 24

SP - 8343

EP - 8347

JO - Organic Letters

JF - Organic Letters

IS - 45

ER -

Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes

Abstract

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