Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts

Aurélie Dos Santos; Laurent El Kaïm; Laurence Grimaud; Romain Ramozzi

doi:10.1055/s-0031-1290312

Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts

Aurélie Dos Santos
, Laurent El Kaïm
, Laurence Grimaud
, Romain Ramozzi

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

The ring opening of aminocyclopropanes triggered by activation with an intramolecular arylpalladium(II) iodide complex is an interesting strategy for the synthesis of nitrogen heterocycles and a valuable Ugi postcondensation-type transformation. Six- and seven-membered-ring cyclic enamines may be obtained.

Original language	English
Pages (from-to)	438-442
Number of pages	5
Journal	Synlett
Issue number	3
DOIs	https://doi.org/10.1055/s-0031-1290312
Publication status	Published - 19 Jan 2012
Externally published	Yes

Keywords

Ugi
Ugi-Smiles
aminocyclopropanes
palladium
ring opening

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10.1055/s-0031-1290312

Cite this

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title = "Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts",

abstract = "The ring opening of aminocyclopropanes triggered by activation with an intramolecular arylpalladium(II) iodide complex is an interesting strategy for the synthesis of nitrogen heterocycles and a valuable Ugi postcondensation-type transformation. Six- and seven-membered-ring cyclic enamines may be obtained.",

keywords = "Ugi, Ugi-Smiles, aminocyclopropanes, palladium, ring opening",

author = "\{Dos Santos\}, Aur{\'e}lie and \{El Ka{\"i}m\}, Laurent and Laurence Grimaud and Romain Ramozzi",

year = "2012",

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doi = "10.1055/s-0031-1290312",

language = "English",

pages = "438--442",

journal = "Synlett",

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T1 - Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts

AU - Dos Santos, Aurélie

AU - El Kaïm, Laurent

AU - Grimaud, Laurence

AU - Ramozzi, Romain

PY - 2012/1/19

Y1 - 2012/1/19

N2 - The ring opening of aminocyclopropanes triggered by activation with an intramolecular arylpalladium(II) iodide complex is an interesting strategy for the synthesis of nitrogen heterocycles and a valuable Ugi postcondensation-type transformation. Six- and seven-membered-ring cyclic enamines may be obtained.

AB - The ring opening of aminocyclopropanes triggered by activation with an intramolecular arylpalladium(II) iodide complex is an interesting strategy for the synthesis of nitrogen heterocycles and a valuable Ugi postcondensation-type transformation. Six- and seven-membered-ring cyclic enamines may be obtained.

KW - Ugi

KW - Ugi-Smiles

KW - aminocyclopropanes

KW - palladium

KW - ring opening

UR - https://www.scopus.com/pages/publications/84856619149

U2 - 10.1055/s-0031-1290312

DO - 10.1055/s-0031-1290312

M3 - Article

AN - SCOPUS:84856619149

SN - 0936-5214

SP - 438

EP - 442

JO - Synlett

JF - Synlett

IS - 3

ER -

Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts

Abstract

Keywords

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