Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Pawel Horeglad; Grégory Nocton; Yaroslav Filinchuk; Jacques Pécaut; Marinella Mazzanti

doi:10.1039/b821398d

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Pawel Horeglad
, Grégory Nocton
, Yaroslav Filinchuk
, Jacques Pécaut
, Marinella Mazzanti

Univ. Joseph Fourier-Grenoble 1
European Synchrotron Radiation Facility

Research output: Contribution to journal › Article › peer-review

Abstract

A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO₂Py₅][KI₂Py₂]} _n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

Original language	English
Pages (from-to)	1843-1845
Number of pages	3
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b821398d
Publication status	Published - 1 Jan 2009
Externally published	Yes

Access to Document

10.1039/b821398d

Cite this

@article{5c5492fc5ade4986a441d591cb940c9e,

title = "Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand",

abstract = "A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor \{[UO2Py5][KI2Py2]\} n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.",

author = "Pawel Horeglad and Gr{\'e}gory Nocton and Yaroslav Filinchuk and Jacques P{\'e}caut and Marinella Mazzanti",

year = "2009",

month = jan,

day = "1",

doi = "10.1039/b821398d",

language = "English",

pages = "1843--1845",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

AU - Horeglad, Pawel

AU - Nocton, Grégory

AU - Filinchuk, Yaroslav

AU - Pécaut, Jacques

AU - Mazzanti, Marinella

PY - 2009/1/1

Y1 - 2009/1/1

N2 - A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO2Py5][KI2Py2]} n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

AB - A pentavalent uranyl complex supported by a bulky dianionic tetradentate (ONNO)-type salan ligand has been prepared by direct synthesis from the iodide precursor {[UO2Py5][KI2Py2]} n, and displays high stability towards disproportionation and ligand dissociation but reactivity towards oxidizing substrates.

U2 - 10.1039/b821398d

DO - 10.1039/b821398d

M3 - Article

AN - SCOPUS:67549107016

SN - 1359-7345

SP - 1843

EP - 1845

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Pentavalent uranyl stabilized by a dianionic bulky tetradentate ligand

Abstract

Access to Document

Fingerprint

Cite this