Photorefractive sol-gel materials

F. Chaput; B. Darracq; J. P. Boilot; D. Riehl; T. Gacoin; M. Canva; Y. Levy; A. Brun

Photorefractive sol-gel materials

F. Chaput
, B. Darracq
, J. P. Boilot
, D. Riehl
, T. Gacoin
, M. Canva
, Y. Levy
, A. Brun

Research output: Contribution to journal › Conference article › peer-review

Abstract

We report the synthesis and characterization of photorefractive sol-gel materials that possess covalently attached push-pull azobenzene and carbazole moieties. Molecular structural characterization of the modified silane monomers was achieved by ¹H NMR and infra red spectroscopy. The second-order nonlinear optical properties of the organic-inorganic hybrid films prepared from modified silane monomers were evaluated by second-harmonic generation. The stabilized value of the second harmonic coefficient, d₃₃, of films poled by corona discharge, at 1064 nm fundamental wavelength was found to be 107 pm/V. Photorefractivity was clearly displayed from a two beam coupling experiment.

Original language	English
Pages (from-to)	583-588
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	435
Publication status	Published - 1 Dec 1996
Event	Proceedings of the 1996 MRS Spring Symposium - San Francisco, CA, USA Duration: 8 Apr 1996 → 12 Apr 1996

Cite this

@article{eff840979dc94dfd9158fa7acda8c85d,

title = "Photorefractive sol-gel materials",

abstract = "We report the synthesis and characterization of photorefractive sol-gel materials that possess covalently attached push-pull azobenzene and carbazole moieties. Molecular structural characterization of the modified silane monomers was achieved by 1H NMR and infra red spectroscopy. The second-order nonlinear optical properties of the organic-inorganic hybrid films prepared from modified silane monomers were evaluated by second-harmonic generation. The stabilized value of the second harmonic coefficient, d33, of films poled by corona discharge, at 1064 nm fundamental wavelength was found to be 107 pm/V. Photorefractivity was clearly displayed from a two beam coupling experiment.",

author = "F. Chaput and B. Darracq and Boilot, \{J. P.\} and D. Riehl and T. Gacoin and M. Canva and Y. Levy and A. Brun",

year = "1996",

month = dec,

day = "1",

language = "English",

volume = "435",

pages = "583--588",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

note = "Proceedings of the 1996 MRS Spring Symposium ; Conference date: 08-04-1996 Through 12-04-1996",

}

TY - JOUR

T1 - Photorefractive sol-gel materials

AU - Chaput, F.

AU - Darracq, B.

AU - Boilot, J. P.

AU - Riehl, D.

AU - Gacoin, T.

AU - Canva, M.

AU - Levy, Y.

AU - Brun, A.

PY - 1996/12/1

Y1 - 1996/12/1

N2 - We report the synthesis and characterization of photorefractive sol-gel materials that possess covalently attached push-pull azobenzene and carbazole moieties. Molecular structural characterization of the modified silane monomers was achieved by 1H NMR and infra red spectroscopy. The second-order nonlinear optical properties of the organic-inorganic hybrid films prepared from modified silane monomers were evaluated by second-harmonic generation. The stabilized value of the second harmonic coefficient, d33, of films poled by corona discharge, at 1064 nm fundamental wavelength was found to be 107 pm/V. Photorefractivity was clearly displayed from a two beam coupling experiment.

AB - We report the synthesis and characterization of photorefractive sol-gel materials that possess covalently attached push-pull azobenzene and carbazole moieties. Molecular structural characterization of the modified silane monomers was achieved by 1H NMR and infra red spectroscopy. The second-order nonlinear optical properties of the organic-inorganic hybrid films prepared from modified silane monomers were evaluated by second-harmonic generation. The stabilized value of the second harmonic coefficient, d33, of films poled by corona discharge, at 1064 nm fundamental wavelength was found to be 107 pm/V. Photorefractivity was clearly displayed from a two beam coupling experiment.

UR - https://www.scopus.com/pages/publications/0030401204

M3 - Conference article

AN - SCOPUS:0030401204

SN - 0272-9172

VL - 435

SP - 583

EP - 588

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

T2 - Proceedings of the 1996 MRS Spring Symposium

Y2 - 8 April 1996 through 12 April 1996

ER -

Photorefractive sol-gel materials

Abstract

Other files and links

Fingerprint

Cite this