Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

Jan Christopher Bernhammer; Gilles Frison; Han Vinh Huynh

doi:10.1039/c4dt01047g

Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ³C,S,C ligands

Jan Christopher Bernhammer
, Gilles Frison
, Han Vinh Huynh

École Polytechnique

Research output: Contribution to journal › Article › peer-review

Abstract

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

Original language	English
Pages (from-to)	8591-8594
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	23
DOIs	https://doi.org/10.1039/c4dt01047g
Publication status	Published - 21 Jun 2014

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title = "Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands",

abstract = "In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.",

author = "Bernhammer, \{Jan Christopher\} and Gilles Frison and Huynh, \{Han Vinh\}",

year = "2014",

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journal = "Dalton Transactions",

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AU - Frison, Gilles

AU - Huynh, Han Vinh

PY - 2014/6/21

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AB - In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

U2 - 10.1039/c4dt01047g

DO - 10.1039/c4dt01047g

M3 - Article

AN - SCOPUS:84901257313

SN - 1477-9226

VL - 43

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EP - 8594

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23

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Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

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Pincer versus pseudopincer: Isomerism in palladium(ii) complexes bearing κ³C,S,C ligands