Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links

Zheng Ni; Abderrahim Yassar; Tarek Antoun; Omar M. Yaghi

doi:10.1021/ja052055c

Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links

Zheng Ni
, Abderrahim Yassar
, Tarek Antoun
, Omar M. Yaghi

Research output: Contribution to journal › Article › peer-review

Abstract

A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu₂(CO₂)₄ paddle-wheel building units and twelve 2,2′:5′,2″-terthiophene-5,5″-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90° linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m²/g, BET surface area 914 m²/g) among materials composed of discrete molecules.

Original language	English
Pages (from-to)	12752-12753
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	37
DOIs	https://doi.org/10.1021/ja052055c
Publication status	Published - 21 Sept 2005
Externally published	Yes

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title = "Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links",

abstract = "A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2′:5′,2″-terthiophene-5,5″-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90° linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m2/g, BET surface area 914 m2/g) among materials composed of discrete molecules.",

author = "Zheng Ni and Abderrahim Yassar and Tarek Antoun and Yaghi, \{Omar M.\}",

year = "2005",

month = sep,

day = "21",

doi = "10.1021/ja052055c",

language = "English",

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pages = "12752--12753",

journal = "Journal of the American Chemical Society",

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T1 - Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links

AU - Ni, Zheng

AU - Yassar, Abderrahim

AU - Antoun, Tarek

AU - Yaghi, Omar M.

PY - 2005/9/21

Y1 - 2005/9/21

N2 - A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2′:5′,2″-terthiophene-5,5″-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90° linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m2/g, BET surface area 914 m2/g) among materials composed of discrete molecules.

AB - A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2′:5′,2″-terthiophene-5,5″-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90° linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m2/g, BET surface area 914 m2/g) among materials composed of discrete molecules.

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DO - 10.1021/ja052055c

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SN - 0002-7863

VL - 127

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EP - 12753

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 37

ER -

Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links

Abstract

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