Preparation and electrochemical properties of polymeric composite electrolytes containing organic clay materials

Seok Kim; Eun Ju Hwang; Jea Rock Lee; Hyung Il Kim; Soo Jin Park

Preparation and electrochemical properties of polymeric composite electrolytes containing organic clay materials

Seok Kim
, Eun Ju Hwang
, Jea Rock Lee
, Hyung Il Kim
, Soo Jin Park

Advanced Materials Division
Center for Convergent Research of Emerging Virus Infection
Department of Industrial Chemistry
Chungnam National University
Inha University

Research output: Contribution to journal › Article › peer-review

Abstract

In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt (LiC1O₄), and sodium montmorillonite (Na⁺-MMT) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of Na⁺-MMT, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

Original language	English
Pages (from-to)	297-301
Number of pages	5
Journal	Polymer (Korea)
Volume	31
Issue number	4
Publication status	Published - 1 Jul 2007
Externally published	Yes

Keywords

Ionic conductivity
Organic montmorillonite
Poly (ethylene oxide)
Polymer/(layered silicate) nanocomposites

Cite this

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title = "Preparation and electrochemical properties of polymeric composite electrolytes containing organic clay materials",

abstract = "In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt (LiC1O4), and sodium montmorillonite (Na+-MMT) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of Na+-MMT, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.",

keywords = "Ionic conductivity, Organic montmorillonite, Poly (ethylene oxide), Polymer/(layered silicate) nanocomposites",

author = "Seok Kim and Hwang, \{Eun Ju\} and Lee, \{Jea Rock\} and Kim, \{Hyung Il\} and Park, \{Soo Jin\}",

year = "2007",

month = jul,

day = "1",

language = "English",

volume = "31",

pages = "297--301",

journal = "Polymer (Korea)",

issn = "0379-153X",

publisher = "Polymer Society of Korea",

number = "4",

}

TY - JOUR

T1 - Preparation and electrochemical properties of polymeric composite electrolytes containing organic clay materials

AU - Kim, Seok

AU - Hwang, Eun Ju

AU - Lee, Jea Rock

AU - Kim, Hyung Il

AU - Park, Soo Jin

PY - 2007/7/1

Y1 - 2007/7/1

N2 - In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt (LiC1O4), and sodium montmorillonite (Na+-MMT) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of Na+-MMT, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

AB - In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt (LiC1O4), and sodium montmorillonite (Na+-MMT) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of Na+-MMT, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

KW - Ionic conductivity

KW - Organic montmorillonite

KW - Poly (ethylene oxide)

KW - Polymer/(layered silicate) nanocomposites

UR - https://www.scopus.com/pages/publications/44649184172

M3 - Article

AN - SCOPUS:44649184172

SN - 0379-153X

VL - 31

SP - 297

EP - 301

JO - Polymer (Korea)

JF - Polymer (Korea)

IS - 4

ER -

Preparation and electrochemical properties of polymeric composite electrolytes containing organic clay materials

Abstract

Keywords

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