Pure acetonitrile as solvent for the efficient electrochemical conversion of aryl bromides in organozinc species and their coupling reaction with acetyl chloride

Hyacinthe Fillon; Erwan Le Gall; Corinne Gosmini; Jacques Périchon

doi:10.1016/S0040-4039(02)01256-X

Pure acetonitrile as solvent for the efficient electrochemical conversion of aryl bromides in organozinc species and their coupling reaction with acetyl chloride

Hyacinthe Fillon
, Erwan Le Gall
, Corinne Gosmini
, Jacques Périchon

Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

Conversion of functionalized aryl bromides in an electrochemical cell fitted with a sacrificial anode and in the presence of cobalt bromide without ligand in acetonitrile as solvent affords the corresponding organozinc species in good yields. Their coupling with acetyl chloride is efficient using a palladium catalyst.

Original language	English
Pages (from-to)	5941-5944
Number of pages	4
Journal	Tetrahedron Letters
Volume	43
Issue number	34
DOIs	https://doi.org/10.1016/S0040-4039(02)01256-X
Publication status	Published - 19 Aug 2002

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@article{f28ad12bb3164e1a8d71befb3c836373,

title = "Pure acetonitrile as solvent for the efficient electrochemical conversion of aryl bromides in organozinc species and their coupling reaction with acetyl chloride",

abstract = "Conversion of functionalized aryl bromides in an electrochemical cell fitted with a sacrificial anode and in the presence of cobalt bromide without ligand in acetonitrile as solvent affords the corresponding organozinc species in good yields. Their coupling with acetyl chloride is efficient using a palladium catalyst.",

author = "Hyacinthe Fillon and \{Le Gall\}, Erwan and Corinne Gosmini and Jacques P{\'e}richon",

year = "2002",

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T1 - Pure acetonitrile as solvent for the efficient electrochemical conversion of aryl bromides in organozinc species and their coupling reaction with acetyl chloride

AU - Fillon, Hyacinthe

AU - Le Gall, Erwan

AU - Gosmini, Corinne

AU - Périchon, Jacques

PY - 2002/8/19

Y1 - 2002/8/19

N2 - Conversion of functionalized aryl bromides in an electrochemical cell fitted with a sacrificial anode and in the presence of cobalt bromide without ligand in acetonitrile as solvent affords the corresponding organozinc species in good yields. Their coupling with acetyl chloride is efficient using a palladium catalyst.

AB - Conversion of functionalized aryl bromides in an electrochemical cell fitted with a sacrificial anode and in the presence of cobalt bromide without ligand in acetonitrile as solvent affords the corresponding organozinc species in good yields. Their coupling with acetyl chloride is efficient using a palladium catalyst.

U2 - 10.1016/S0040-4039(02)01256-X

DO - 10.1016/S0040-4039(02)01256-X

M3 - Article

AN - SCOPUS:0037136099

SN - 0040-4039

VL - 43

SP - 5941

EP - 5944

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 34

ER -

Pure acetonitrile as solvent for the efficient electrochemical conversion of aryl bromides in organozinc species and their coupling reaction with acetyl chloride

Abstract

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