Pyrazine-Fused Bis(tetrathiafulvalenes)

Khalid Lahlil; Alec Moradpour; Claude Merienne; Christopher Bowlas

doi:10.1021/jo00105a018

Pyrazine-Fused Bis(tetrathiafulvalenes)

Khalid Lahlil
, Alec Moradpour
, Claude Merienne
, Christopher Bowlas

Research output: Contribution to journal › Article › peer-review

Abstract

The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

Original language	English
Pages (from-to)	8030-8033
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	59
Issue number	26
DOIs	https://doi.org/10.1021/jo00105a018
Publication status	Published - 1 Dec 1994
Externally published	Yes

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title = "Pyrazine-Fused Bis(tetrathiafulvalenes)",

abstract = "The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.",

author = "Khalid Lahlil and Alec Moradpour and Claude Merienne and Christopher Bowlas",

year = "1994",

month = dec,

day = "1",

doi = "10.1021/jo00105a018",

language = "English",

volume = "59",

pages = "8030--8033",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

number = "26",

}

TY - JOUR

T1 - Pyrazine-Fused Bis(tetrathiafulvalenes)

AU - Lahlil, Khalid

AU - Moradpour, Alec

AU - Merienne, Claude

AU - Bowlas, Christopher

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

AB - The TTF-like bidentate sulfur nucleophiles 13a,b have been prepared from the corresponding 4,5-dialkyl-1,3-dithiole S-oxides 11a,b, obtained by the oxidation of the parent 1,3-dithioles 10a,b. The aromatic nucleophilic substitutions of tetrachloropyrazine by these nucleophiles 13a,b yield, in a single step, the unsymmetrically substituted pyrazino-TTF 8 or the pyrazine-fused bis-TTF 9a,b depending on the stoeichiometries of the reactions. The electrochemical properties of these new donors, obtained by cyclic voltammetry, are also reported.

U2 - 10.1021/jo00105a018

DO - 10.1021/jo00105a018

M3 - Article

AN - SCOPUS:4043092006

SN - 0022-3263

VL - 59

SP - 8030

EP - 8033

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 26

ER -

Pyrazine-Fused Bis(tetrathiafulvalenes)

Abstract

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