Pyrrolidinone and piperidinone isocyanides from isocyano esters

Madjid Ait Sidhoum; Aurélie Dos Santos; Laurent El Kaïm; Laetitia Legras

doi:10.1002/ejoc.201402572

Pyrrolidinone and piperidinone isocyanides from isocyano esters

Madjid Ait Sidhoum
, Aurélie Dos Santos
, Laurent El Kaïm
, Laetitia Legras

Unité Chimie et Procédés

Research output: Contribution to journal › Article › peer-review

Abstract

The alkylation of isocyano esters with 1,2- and 1,3-dibromoalkanes affords bromo isocyanides. Under treatment with various amines the latter form new isocyano-substituted lactams, which can be further used in Passerini or Ugi reactions.

Original language	English
Pages (from-to)	4949-4952
Number of pages	4
Journal	European Journal of Organic Chemistry
Volume	2014
Issue number	23
DOIs	https://doi.org/10.1002/ejoc.201402572
Publication status	Published - 1 Jan 2014
Externally published	Yes

Keywords

Amines
Isocyanoacetates
Lactams
Multicomponent reactions
Nitrogen heterocycles

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10.1002/ejoc.201402572

Cite this

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title = "Pyrrolidinone and piperidinone isocyanides from isocyano esters",

abstract = "The alkylation of isocyano esters with 1,2- and 1,3-dibromoalkanes affords bromo isocyanides. Under treatment with various amines the latter form new isocyano-substituted lactams, which can be further used in Passerini or Ugi reactions.",

keywords = "Amines, Isocyanoacetates, Lactams, Multicomponent reactions, Nitrogen heterocycles",

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doi = "10.1002/ejoc.201402572",

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AU - Sidhoum, Madjid Ait

AU - Dos Santos, Aurélie

AU - El Kaïm, Laurent

AU - Legras, Laetitia

PY - 2014/1/1

Y1 - 2014/1/1

N2 - The alkylation of isocyano esters with 1,2- and 1,3-dibromoalkanes affords bromo isocyanides. Under treatment with various amines the latter form new isocyano-substituted lactams, which can be further used in Passerini or Ugi reactions.

AB - The alkylation of isocyano esters with 1,2- and 1,3-dibromoalkanes affords bromo isocyanides. Under treatment with various amines the latter form new isocyano-substituted lactams, which can be further used in Passerini or Ugi reactions.

KW - Amines

KW - Isocyanoacetates

KW - Lactams

KW - Multicomponent reactions

KW - Nitrogen heterocycles

UR - https://www.scopus.com/pages/publications/84940256074

U2 - 10.1002/ejoc.201402572

DO - 10.1002/ejoc.201402572

M3 - Article

AN - SCOPUS:84940256074

SN - 1434-193X

VL - 2014

SP - 4949

EP - 4952

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 23

ER -

Pyrrolidinone and piperidinone isocyanides from isocyano esters

Abstract

Keywords

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