Radical arylaminomethylation of unactivated alkenes

Frédéric Lebreux; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1021/ol901055j

Radical arylaminomethylation of unactivated alkenes

Frédéric Lebreux, Béatrice Quiclet-Sire, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

Xanthates derived from open chain or cyclic N-chloromethylanllldes are capable of adding to various unactlvated alkenes to give adducts which, In suitable cases, can be made to undergo ring closure onto the aromatic ring. This flexible arylamlnomethylatlon of alkenes allows the rapid synthesis of open chain or polycycllc aniline derivatives.

Original language	English
Pages (from-to)	2844-2847
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	13
DOIs	https://doi.org/10.1021/ol901055j
Publication status	Published - 2 Jul 2009
Externally published	Yes

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10.1021/ol901055j

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title = "Radical arylaminomethylation of unactivated alkenes",

abstract = "Xanthates derived from open chain or cyclic N-chloromethylanllldes are capable of adding to various unactlvated alkenes to give adducts which, In suitable cases, can be made to undergo ring closure onto the aromatic ring. This flexible arylamlnomethylatlon of alkenes allows the rapid synthesis of open chain or polycycllc aniline derivatives.",

author = "Fr{\'e}d{\'e}ric Lebreux and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2009",

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doi = "10.1021/ol901055j",

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journal = "Organic Letters",

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T1 - Radical arylaminomethylation of unactivated alkenes

AU - Lebreux, Frédéric

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2009/7/2

Y1 - 2009/7/2

N2 - Xanthates derived from open chain or cyclic N-chloromethylanllldes are capable of adding to various unactlvated alkenes to give adducts which, In suitable cases, can be made to undergo ring closure onto the aromatic ring. This flexible arylamlnomethylatlon of alkenes allows the rapid synthesis of open chain or polycycllc aniline derivatives.

AB - Xanthates derived from open chain or cyclic N-chloromethylanllldes are capable of adding to various unactlvated alkenes to give adducts which, In suitable cases, can be made to undergo ring closure onto the aromatic ring. This flexible arylamlnomethylatlon of alkenes allows the rapid synthesis of open chain or polycycllc aniline derivatives.

U2 - 10.1021/ol901055j

DO - 10.1021/ol901055j

M3 - Article

AN - SCOPUS:67649472594

SN - 1523-7060

VL - 11

SP - 2844

EP - 2847

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

Radical arylaminomethylation of unactivated alkenes

Abstract

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