Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes

Matthieu Corbet; Zorana Ferjančić; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1021/ol801348u

Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes

Matthieu Corbet
, Zorana Ferjančić
, Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

(Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.

Original language	English
Pages (from-to)	3579-3582
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	16
DOIs	https://doi.org/10.1021/ol801348u
Publication status	Published - 1 Jan 2008
Externally published	Yes

Access to Document

10.1021/ol801348u

Cite this

@article{ca2eb340e8324f99bc3e5a792533cc25,

title = "Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes",

abstract = "(Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.",

author = "Matthieu Corbet and Zorana Ferjan{\v c}i{\'c} and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "2008",

month = jan,

day = "1",

doi = "10.1021/ol801348u",

language = "English",

volume = "10",

pages = "3579--3582",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes

AU - Corbet, Matthieu

AU - Ferjančić, Zorana

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2008/1/1

Y1 - 2008/1/1

N2 - (Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.

AB - (Chemical Equation Presented) Xanthates have been readily converted into o-chlorophenyl thioethers using a one-step procedure conducted under radical conditions. In some selected cases, these aryl thioethers were successfully oxidized to the corresponding sulfoxides and sulfenic acid elimination afforded the corresponding vinylsilanes.

U2 - 10.1021/ol801348u

DO - 10.1021/ol801348u

M3 - Article

C2 - 18646770

AN - SCOPUS:54049135278

SN - 1523-7060

VL - 10

SP - 3579

EP - 3582

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Radical, one-step approach to o-chlorophenyl thioethers from xanthates. A rapid access to vinylsilanes

Abstract

Access to Document

Fingerprint

Cite this