Radicals from aldehydes: A convergent access to dienes and δ-lactones

Sharanjeet K. Bagal; Lucie Tournier; Samir Z. Zard

doi:10.1055/s-2006-941582

Radicals from aldehydes: A convergent access to dienes and δ-lactones

Sharanjeet K. Bagal
, Lucie Tournier
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated δ-lactones.

Original language	English
Pages (from-to)	1485-1490
Number of pages	6
Journal	Synlett
Issue number	10
DOIs	https://doi.org/10.1055/s-2006-941582
Publication status	Published - 21 Jun 2006
Externally published	Yes

Keywords

Aldehydes
Dienes
Lactones
Radical reactions
Xanthates

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10.1055/s-2006-941582

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title = "Radicals from aldehydes: A convergent access to dienes and δ-lactones",

abstract = "A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated δ-lactones.",

keywords = "Aldehydes, Dienes, Lactones, Radical reactions, Xanthates",

author = "Bagal, \{Sharanjeet K.\} and Lucie Tournier and Zard, \{Samir Z.\}",

year = "2006",

month = jun,

day = "21",

doi = "10.1055/s-2006-941582",

language = "English",

pages = "1485--1490",

journal = "Synlett",

issn = "0936-5214",

number = "10",

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TY - JOUR

T1 - Radicals from aldehydes

T2 - A convergent access to dienes and δ-lactones

AU - Bagal, Sharanjeet K.

AU - Tournier, Lucie

AU - Zard, Samir Z.

PY - 2006/6/21

Y1 - 2006/6/21

N2 - A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated δ-lactones.

AB - A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated δ-lactones.

KW - Aldehydes

KW - Dienes

KW - Lactones

KW - Radical reactions

KW - Xanthates

UR - https://www.scopus.com/pages/publications/33745712079

U2 - 10.1055/s-2006-941582

DO - 10.1055/s-2006-941582

M3 - Article

AN - SCOPUS:33745712079

SN - 0936-5214

SP - 1485

EP - 1490

JO - Synlett

JF - Synlett

IS - 10

ER -

Radicals from aldehydes: A convergent access to dienes and δ-lactones

Abstract

Keywords

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