Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl2(PEt 3)(PPhCPh=CPh)], cis-[Ptl(PPh3)(CPh=CPhPPhMe)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5]

Salih S. Al Juaid; Duncan Carmichael; Peter B. Hitchcock; Angela Marinetti; François Mathey; John F. Nixon

doi:10.1039/DT9910000905

Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl₂(PEt ₃)(PPhCPh=CPh)], cis-[Ptl(PPh₃)(CPh=CPhPPhMe)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅]

Salih S. Al Juaid
, Duncan Carmichael
, Peter B. Hitchcock
, Angela Marinetti
, François Mathey
, John F. Nixon

Research output: Contribution to journal › Article › peer-review

Abstract

The phosphirene ring system PhPCPh=CPh 1 undergoes unidentate ligation and/or insertion reactions with a variety of platinum metal complexes. Insertion reactions also occur with the [W(CO)₅] adduct of 1. Detailed NMR and single-crystal X-ray studies on [PtCl₂(PEt₃)(PPhCPh=CPh)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅] confirm the nature of both types of complexes. The compounds [{PtCl₂(PEt ₃)}₂] and Mel react with [Pt(PPh₃) ₂(CPh=CPhPPh)] to give [(Ph₃P)₂Pt(CPh=CPhPPh) PtCl₂(PEt₃)] and [Ptl(PPh₃)(CPh=CPhPPhMe)], respectively, the latter being characterised by a single-crystal X-ray diffraction study.

Original language	English
Pages (from-to)	905-915
Number of pages	11
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	S
DOIs	https://doi.org/10.1039/DT9910000905
Publication status	Published - 1 Dec 1991
Externally published	Yes

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Al Juaid, S. S., Carmichael, D., Hitchcock, P. B., Marinetti, A., Mathey, F., & Nixon, J. F. (1991). Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl₂(PEt ₃)(PPhCPh=CPh)], cis-[Ptl(PPh₃)(CPh=CPhPPhMe)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅]. Journal of the Chemical Society - Dalton Transactions, (S), 905-915. https://doi.org/10.1039/DT9910000905

@article{ae817698b30a4499bb1c55be57b40d99,

title = "Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl2(PEt 3)(PPhCPh=CPh)], cis-[Ptl(PPh3)(CPh=CPhPPhMe)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5]",

abstract = "The phosphirene ring system PhPCPh=CPh 1 undergoes unidentate ligation and/or insertion reactions with a variety of platinum metal complexes. Insertion reactions also occur with the [W(CO)5] adduct of 1. Detailed NMR and single-crystal X-ray studies on [PtCl2(PEt3)(PPhCPh=CPh)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5] confirm the nature of both types of complexes. The compounds [\{PtCl2(PEt 3)\}2] and Mel react with [Pt(PPh3) 2(CPh=CPhPPh)] to give [(Ph3P)2Pt(CPh=CPhPPh) PtCl2(PEt3)] and [Ptl(PPh3)(CPh=CPhPPhMe)], respectively, the latter being characterised by a single-crystal X-ray diffraction study.",

author = "\{Al Juaid\}, \{Salih S.\} and Duncan Carmichael and Hitchcock, \{Peter B.\} and Angela Marinetti and Fran{\c c}ois Mathey and Nixon, \{John F.\}",

year = "1991",

month = dec,

day = "1",

doi = "10.1039/DT9910000905",

language = "English",

pages = "905--915",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "0300-9246",

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Al Juaid, SS, Carmichael, D, Hitchcock, PB, Marinetti, A, Mathey, F & Nixon, JF 1991, 'Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl₂(PEt ₃)(PPhCPh=CPh)], cis-[Ptl(PPh₃)(CPh=CPhPPhMe)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅]', Journal of the Chemical Society - Dalton Transactions, no. S, pp. 905-915. https://doi.org/10.1039/DT9910000905

Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl₂(PEt ₃)(PPhCPh=CPh)], cis-[Ptl(PPh₃)(CPh=CPhPPhMe)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅]. / Al Juaid, Salih S.; Carmichael, Duncan; Hitchcock, Peter B. et al.
In: Journal of the Chemical Society - Dalton Transactions, No. S, 01.12.1991, p. 905-915.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl2(PEt 3)(PPhCPh=CPh)], cis-[Ptl(PPh3)(CPh=CPhPPhMe)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5]

AU - Al Juaid, Salih S.

AU - Carmichael, Duncan

AU - Hitchcock, Peter B.

AU - Marinetti, Angela

AU - Mathey, François

AU - Nixon, John F.

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The phosphirene ring system PhPCPh=CPh 1 undergoes unidentate ligation and/or insertion reactions with a variety of platinum metal complexes. Insertion reactions also occur with the [W(CO)5] adduct of 1. Detailed NMR and single-crystal X-ray studies on [PtCl2(PEt3)(PPhCPh=CPh)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5] confirm the nature of both types of complexes. The compounds [{PtCl2(PEt 3)}2] and Mel react with [Pt(PPh3) 2(CPh=CPhPPh)] to give [(Ph3P)2Pt(CPh=CPhPPh) PtCl2(PEt3)] and [Ptl(PPh3)(CPh=CPhPPhMe)], respectively, the latter being characterised by a single-crystal X-ray diffraction study.

AB - The phosphirene ring system PhPCPh=CPh 1 undergoes unidentate ligation and/or insertion reactions with a variety of platinum metal complexes. Insertion reactions also occur with the [W(CO)5] adduct of 1. Detailed NMR and single-crystal X-ray studies on [PtCl2(PEt3)(PPhCPh=CPh)] and [(Et3P)2Pt(CPh=CPhPPh)W(CO)5] confirm the nature of both types of complexes. The compounds [{PtCl2(PEt 3)}2] and Mel react with [Pt(PPh3) 2(CPh=CPhPPh)] to give [(Ph3P)2Pt(CPh=CPhPPh) PtCl2(PEt3)] and [Ptl(PPh3)(CPh=CPhPPhMe)], respectively, the latter being characterised by a single-crystal X-ray diffraction study.

U2 - 10.1039/DT9910000905

DO - 10.1039/DT9910000905

M3 - Article

AN - SCOPUS:37049076229

SN - 0300-9246

SP - 905

EP - 915

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - S

ER -

Al Juaid SS, Carmichael D, Hitchcock PB, Marinetti A, Mathey F, Nixon JF. Reactions of zero- and di-valent platinum metal complexes with phosphirene ring systems. Crystal structures of cis-[PtCl₂(PEt ₃)(PPhCPh=CPh)], cis-[Ptl(PPh₃)(CPh=CPhPPhMe)] and [(Et₃P)₂Pt(CPh=CPhPPh)W(CO)₅]. Journal of the Chemical Society - Dalton Transactions. 1991 Dec 1;(S):905-915. doi: 10.1039/DT9910000905