Recent advances in electrophilic amination reactions

Martin Corpet; Corinne Gosmini

doi:10.1055/s-0034-1378373

Recent advances in electrophilic amination reactions

Martin Corpet, Corinne Gosmini

CNRS

Research output: Contribution to journal › Review article › peer-review

Abstract

Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation of C-N bonds. Recently, a significant number of useful methodologies have been reported, in particular, examples using transition-metal catalysis. This review summarizes the latest developments in this field, with a focus on very recent advances. 1 Introduction 2 Reactions with Stoichiometric Organometallic Reagents 2.1 Organoboron Nucleophiles 2.2 Zirconium Derivatives 2.3 Silicon Derivatives 2.4 Grignard Reagents 2.5 Organozinc Reagents 3 Catalytic Organometallic Species 3.1 C-H Activation Reactions 3.2 Heterocycle Synthesis via Addition/Amination Sequences 3.3 Narasaka-Heck (or Amino-Heck) Reactions 4 Enolates as Nucleophiles 5 Conclusion.

Original language	English
Article number	ss-2014-m0206-sr
Pages (from-to)	2258-2271
Number of pages	14
Journal	Synthesis
Volume	46
Issue number	17
DOIs	https://doi.org/10.1055/s-0034-1378373
Publication status	Published - 1 Jan 2014
Externally published	Yes

Keywords

C-H activation
amination
catalysis
heterocycles
organometallic reagents

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10.1055/s-0034-1378373

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title = "Recent advances in electrophilic amination reactions",

abstract = "Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation of C-N bonds. Recently, a significant number of useful methodologies have been reported, in particular, examples using transition-metal catalysis. This review summarizes the latest developments in this field, with a focus on very recent advances. 1 Introduction 2 Reactions with Stoichiometric Organometallic Reagents 2.1 Organoboron Nucleophiles 2.2 Zirconium Derivatives 2.3 Silicon Derivatives 2.4 Grignard Reagents 2.5 Organozinc Reagents 3 Catalytic Organometallic Species 3.1 C-H Activation Reactions 3.2 Heterocycle Synthesis via Addition/Amination Sequences 3.3 Narasaka-Heck (or Amino-Heck) Reactions 4 Enolates as Nucleophiles 5 Conclusion.",

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AU - Gosmini, Corinne

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N2 - Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation of C-N bonds. Recently, a significant number of useful methodologies have been reported, in particular, examples using transition-metal catalysis. This review summarizes the latest developments in this field, with a focus on very recent advances. 1 Introduction 2 Reactions with Stoichiometric Organometallic Reagents 2.1 Organoboron Nucleophiles 2.2 Zirconium Derivatives 2.3 Silicon Derivatives 2.4 Grignard Reagents 2.5 Organozinc Reagents 3 Catalytic Organometallic Species 3.1 C-H Activation Reactions 3.2 Heterocycle Synthesis via Addition/Amination Sequences 3.3 Narasaka-Heck (or Amino-Heck) Reactions 4 Enolates as Nucleophiles 5 Conclusion.

AB - Electrophilic nitrogen sources are an increasingly popular class of reagents for the formation of C-N bonds. Recently, a significant number of useful methodologies have been reported, in particular, examples using transition-metal catalysis. This review summarizes the latest developments in this field, with a focus on very recent advances. 1 Introduction 2 Reactions with Stoichiometric Organometallic Reagents 2.1 Organoboron Nucleophiles 2.2 Zirconium Derivatives 2.3 Silicon Derivatives 2.4 Grignard Reagents 2.5 Organozinc Reagents 3 Catalytic Organometallic Species 3.1 C-H Activation Reactions 3.2 Heterocycle Synthesis via Addition/Amination Sequences 3.3 Narasaka-Heck (or Amino-Heck) Reactions 4 Enolates as Nucleophiles 5 Conclusion.

KW - C-H activation

KW - amination

KW - catalysis

KW - heterocycles

KW - organometallic reagents

U2 - 10.1055/s-0034-1378373

DO - 10.1055/s-0034-1378373

M3 - Review article

AN - SCOPUS:84906785907

SN - 0039-7881

VL - 46

SP - 2258

EP - 2271

JO - Synthesis

JF - Synthesis

IS - 17

M1 - ss-2014-m0206-sr

ER -

Recent advances in electrophilic amination reactions

Abstract

Keywords

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