Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Derek HR Barton; Timothy Bowles; Suren Husinec; Judith E. Forbes; Antonia Llobera; Alexander EA Porter; Samir Z. Zard

doi:10.1016/0040-4039(88)85157-8

Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Derek HR Barton
, Timothy Bowles
, Suren Husinec
, Judith E. Forbes
, Antonia Llobera
, Alexander EA Porter
, Samir Z. Zard

Department of Chemistry
Texas A&M University
Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

Original language	English
Pages (from-to)	3343-3346
Number of pages	4
Journal	Tetrahedron Letters
Volume	29
Issue number	27
DOIs	https://doi.org/10.1016/0040-4039(88)85157-8
Publication status	Published - 1 Jan 1988
Externally published	Yes

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@article{4e97e781b523486c8b1229790d86e8d3,

title = "Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles",

abstract = "Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.",

author = "Barton, \{Derek HR\} and Timothy Bowles and Suren Husinec and Forbes, \{Judith E.\} and Antonia Llobera and Porter, \{Alexander EA\} and Zard, \{Samir Z.\}",

year = "1988",

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doi = "10.1016/0040-4039(88)85157-8",

language = "English",

volume = "29",

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journal = "Tetrahedron Letters",

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T1 - Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

AU - Barton, Derek HR

AU - Bowles, Timothy

AU - Husinec, Suren

AU - Forbes, Judith E.

AU - Llobera, Antonia

AU - Porter, Alexander EA

AU - Zard, Samir Z.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

AB - Reduction of ketoximes using anhydrous titanium-(III)-acetate in the presence of mixed formic-acetic anhydride yields N-formyl enamines which may be dehydrated to vinyl isonitriles.

U2 - 10.1016/0040-4039(88)85157-8

DO - 10.1016/0040-4039(88)85157-8

M3 - Article

AN - SCOPUS:0001682833

SN - 0040-4039

VL - 29

SP - 3343

EP - 3346

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 27

ER -

Reductive formylation of oximes; an approach to the synthesis of vinyl isonitriles

Abstract

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