Regio- And diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

Juba Ghouilem; Rémi Franco; Pascal Retailleau; Mouad Alami; Vincent Gandon; Samir Messaoudi

doi:10.1039/d0cc02175j

Regio- And diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

Juba Ghouilem, Rémi Franco, Pascal Retailleau, Mouad Alami, Vincent Gandon, Samir Messaoudi

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

Original language	English
Pages (from-to)	7175-7178
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	52
DOIs	https://doi.org/10.1039/d0cc02175j
Publication status	Published - 4 Jul 2020
Externally published	Yes

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title = "Regio- And diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides",

abstract = "An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.",

author = "Juba Ghouilem and R{\'e}mi Franco and Pascal Retailleau and Mouad Alami and Vincent Gandon and Samir Messaoudi",

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AU - Ghouilem, Juba

AU - Franco, Rémi

AU - Retailleau, Pascal

AU - Alami, Mouad

AU - Gandon, Vincent

AU - Messaoudi, Samir

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/7/4

Y1 - 2020/7/4

N2 - An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

AB - An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

U2 - 10.1039/d0cc02175j

DO - 10.1039/d0cc02175j

M3 - Article

C2 - 32463030

AN - SCOPUS:85087467841

SN - 1359-7345

VL - 56

SP - 7175

EP - 7178

JO - Chemical Communications

JF - Chemical Communications

IS - 52

ER -

Regio- And diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

Abstract

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