Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

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Abstract

The reaction of a series of organolanthanide fragments of samarium and thulium with phenanthroline is reported. All adducts couple in the 4-position of the phenanthroline ligand to yield the 4-4′ dimers when they crystallize. The analysis of the solution structure revealed a thermally reversible C-C coupling in all cases.

Original languageEnglish
Pages (from-to)3578-3581
Number of pages4
JournalChemical Communications
Volume51
Issue number17
DOIs
Publication statusPublished - 28 Feb 2015
Externally publishedYes

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