Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Ravi Yadav; Thomas Simler; Michael T. Gamer; Ralf Köppe; Peter W. Roesky

doi:10.1039/c9cc02350j

Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Ravi Yadav
, Thomas Simler
, Michael T. Gamer
, Ralf Köppe
, Peter W. Roesky

Institute of Meteorology and Climate Research

Research output: Contribution to journal › Article › peer-review

Abstract

The reduction of M₂(CO)₁₀ (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

Original language	English
Pages (from-to)	5765-5768
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	41
DOIs	https://doi.org/10.1039/c9cc02350j
Publication status	Published - 1 Jan 2019
Externally published	Yes

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abstract = "The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.",

author = "Ravi Yadav and Thomas Simler and Gamer, \{Michael T.\} and Ralf K{\"o}ppe and Roesky, \{Peter W.\}",

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AU - Köppe, Ralf

AU - Roesky, Peter W.

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AB - The reduction of M2(CO)10 (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

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Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Abstract

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