Second generation biofuels: Thermochemistry of glucose and fructose

A. Osmont; L. Catoire; P. Escot Bocanegra; I. Gökalp; B. Thollas; J. A. Kozinski

doi:10.1016/j.combustflame.2009.12.002

Second generation biofuels: Thermochemistry of glucose and fructose

A. Osmont, L. Catoire, P. Escot Bocanegra, I. Gökalp, B. Thollas, J. A. Kozinski

Research output: Contribution to journal › Article › peer-review

Abstract

The energetic conversion of biomass into syngas or biogas is a more and more important topic. In the framework of these studies, improved understanding of glucose and fructose thermal decomposition and oxidation appears crucial. For this task, thermodynamic data are needed to make possible, for instance, the building of a detailed chemical kinetic model of glucose and fructose reactivity at high temperature. A semitheoretical protocol, presented elsewhere, is used for the estimation of the thermodynamic data of glucose and fructose in the gas phase. Five isomers of glucose and five isomers of fructose are considered and the lowest-energy conformers are found to be β-. d-glucopyranose for glucose and β-. d-fructopyranose for fructose. The data for all 10 isomers are provided in the CHEMKIN-NASA format.

Original language	English
Pages (from-to)	1230-1234
Number of pages	5
Journal	Combustion and Flame
Volume	157
Issue number	6
DOIs	https://doi.org/10.1016/j.combustflame.2009.12.002
Publication status	Published - 1 Jun 2010
Externally published	Yes

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10.1016/j.combustflame.2009.12.002

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title = "Second generation biofuels: Thermochemistry of glucose and fructose",

abstract = "The energetic conversion of biomass into syngas or biogas is a more and more important topic. In the framework of these studies, improved understanding of glucose and fructose thermal decomposition and oxidation appears crucial. For this task, thermodynamic data are needed to make possible, for instance, the building of a detailed chemical kinetic model of glucose and fructose reactivity at high temperature. A semitheoretical protocol, presented elsewhere, is used for the estimation of the thermodynamic data of glucose and fructose in the gas phase. Five isomers of glucose and five isomers of fructose are considered and the lowest-energy conformers are found to be β-. d-glucopyranose for glucose and β-. d-fructopyranose for fructose. The data for all 10 isomers are provided in the CHEMKIN-NASA format.",

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TY - JOUR

T1 - Second generation biofuels

T2 - Thermochemistry of glucose and fructose

AU - Osmont, A.

AU - Catoire, L.

AU - Escot Bocanegra, P.

AU - Gökalp, I.

AU - Thollas, B.

AU - Kozinski, J. A.

PY - 2010/6/1

Y1 - 2010/6/1

N2 - The energetic conversion of biomass into syngas or biogas is a more and more important topic. In the framework of these studies, improved understanding of glucose and fructose thermal decomposition and oxidation appears crucial. For this task, thermodynamic data are needed to make possible, for instance, the building of a detailed chemical kinetic model of glucose and fructose reactivity at high temperature. A semitheoretical protocol, presented elsewhere, is used for the estimation of the thermodynamic data of glucose and fructose in the gas phase. Five isomers of glucose and five isomers of fructose are considered and the lowest-energy conformers are found to be β-. d-glucopyranose for glucose and β-. d-fructopyranose for fructose. The data for all 10 isomers are provided in the CHEMKIN-NASA format.

AB - The energetic conversion of biomass into syngas or biogas is a more and more important topic. In the framework of these studies, improved understanding of glucose and fructose thermal decomposition and oxidation appears crucial. For this task, thermodynamic data are needed to make possible, for instance, the building of a detailed chemical kinetic model of glucose and fructose reactivity at high temperature. A semitheoretical protocol, presented elsewhere, is used for the estimation of the thermodynamic data of glucose and fructose in the gas phase. Five isomers of glucose and five isomers of fructose are considered and the lowest-energy conformers are found to be β-. d-glucopyranose for glucose and β-. d-fructopyranose for fructose. The data for all 10 isomers are provided in the CHEMKIN-NASA format.

U2 - 10.1016/j.combustflame.2009.12.002

DO - 10.1016/j.combustflame.2009.12.002

M3 - Article

AN - SCOPUS:77950339791

SN - 0010-2180

VL - 157

SP - 1230

EP - 1234

JO - Combustion and Flame

JF - Combustion and Flame

IS - 6

ER -

Second generation biofuels: Thermochemistry of glucose and fructose

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