Selective access to electron donating group substituted (η5-cyclohexadienyl)Mn(CO)3 complexes by bimetallic manganese-palladium activation

Audrey Auffrant; Damien Prim; Françoise Rose-Munch; Eric Rose; Jacqueline Vaissermann

doi:10.1021/om0202773

Selective access to electron donating group substituted (η⁵-cyclohexadienyl)Mn(CO)₃ complexes by bimetallic manganese-palladium activation

Audrey Auffrant, Damien Prim, Françoise Rose-Munch, Eric Rose, Jacqueline Vaissermann

Research output: Contribution to journal › Article › peer-review

Abstract

Unprecedented (η⁵-cyclohexadienyl)Mn(CO)₃ complexes bearing an electron-donating group at the end of the π system have been selectively prepared using Pd catalysis and primary, secondary cyclic, and acyclic amines. This catalytic methodology has been extended to O-, S-, and P-based derivatives. The X-ray structure of one coupling product exhibits an unusual conformation in its η⁵ system.

Original language	English
Pages (from-to)	3500-3502
Number of pages	3
Journal	Organometallics
Volume	21
Issue number	17
DOIs	https://doi.org/10.1021/om0202773
Publication status	Published - 19 Aug 2002

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10.1021/om0202773

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title = "Selective access to electron donating group substituted (η5-cyclohexadienyl)Mn(CO)3 complexes by bimetallic manganese-palladium activation",

abstract = "Unprecedented (η5-cyclohexadienyl)Mn(CO)3 complexes bearing an electron-donating group at the end of the π system have been selectively prepared using Pd catalysis and primary, secondary cyclic, and acyclic amines. This catalytic methodology has been extended to O-, S-, and P-based derivatives. The X-ray structure of one coupling product exhibits an unusual conformation in its η5 system.",

author = "Audrey Auffrant and Damien Prim and Fran{\c c}oise Rose-Munch and Eric Rose and Jacqueline Vaissermann",

year = "2002",

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T1 - Selective access to electron donating group substituted (η5-cyclohexadienyl)Mn(CO)3 complexes by bimetallic manganese-palladium activation

AU - Auffrant, Audrey

AU - Prim, Damien

AU - Rose-Munch, Françoise

AU - Rose, Eric

AU - Vaissermann, Jacqueline

PY - 2002/8/19

Y1 - 2002/8/19

N2 - Unprecedented (η5-cyclohexadienyl)Mn(CO)3 complexes bearing an electron-donating group at the end of the π system have been selectively prepared using Pd catalysis and primary, secondary cyclic, and acyclic amines. This catalytic methodology has been extended to O-, S-, and P-based derivatives. The X-ray structure of one coupling product exhibits an unusual conformation in its η5 system.

AB - Unprecedented (η5-cyclohexadienyl)Mn(CO)3 complexes bearing an electron-donating group at the end of the π system have been selectively prepared using Pd catalysis and primary, secondary cyclic, and acyclic amines. This catalytic methodology has been extended to O-, S-, and P-based derivatives. The X-ray structure of one coupling product exhibits an unusual conformation in its η5 system.

U2 - 10.1021/om0202773

DO - 10.1021/om0202773

M3 - Article

AN - SCOPUS:0038003207

SN - 0276-7333

VL - 21

SP - 3500

EP - 3502

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Selective access to electron donating group substituted (η5-cyclohexadienyl)Mn(CO)3 complexes by bimetallic manganese-palladium activation

Abstract

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Selective access to electron donating group substituted (η⁵-cyclohexadienyl)Mn(CO)₃ complexes by bimetallic manganese-palladium activation