Single-Crystal Nanowire Cesium Tin Triiodide Perovskite Solar Cell

This work reports for the first time a highly efficient single-crystal cesium tin triiodide (CsSnI₃) perovskite nanowire solar cell. With a perfect lattice structure, low carrier trap density (≈5 × 10¹⁰ cm⁻³), long carrier lifetime (46.7 ns), and excellent carrier mobility (>600 cm² V⁻¹ s⁻¹), single-crystal CsSnI₃ perovskite nanowires enable a very attractive feature for flexible perovskite photovoltaics to power active micro-scale electronic devices. Using CsSnI₃ single-crystal nanowire in conjunction with highly conductive wide bandgap semiconductors as front-surface-field layers, an unprecedented efficiency of 11.7% under AM 1.5G illumination is achieved. This work demonstrates the feasibility of all-inorganic tin-based perovskite solar cells via crystallinity and device-structure improvement for the high-performance, and thus paves the way for the energy supply to flexible wearable devices in the future.