Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

L. D. Miranda; S. Z. Zard

doi:10.1039/b101053k

Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

L. D. Miranda
, S. Z. Zard

Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an enetype concerted transformation of the intermediate mono-substituted diimide.

Original language	English
Pages (from-to)	1068-1069
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b101053k
Publication status	Published - 21 Jun 2001

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title = "Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones",

abstract = "The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an enetype concerted transformation of the intermediate mono-substituted diimide.",

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AB - The previously described, highly stereoselective ring-closure of δ-unsaturated tosylhydrazones upon reduction with borohydride may not be a radical process but rather an enetype concerted transformation of the intermediate mono-substituted diimide.

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DO - 10.1039/b101053k

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JO - Chemical Communications

JF - Chemical Communications

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Some mechanistic observations on the borohydride mediated reductive cyclisation of tosylhydrazones

Abstract

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