Structural, optical, and theoretical studies of a thermochromic organic crystal with reversibly variable second harmonic generation

Michel Sliwa; Arnaud Spangenberg; Isabelle Malfant; Pascal G. Lacroix; Rémi Métivier; Robert B. Pansu; Keitaro Nakatani

doi:10.1021/cm800093a

Structural, optical, and theoretical studies of a thermochromic organic crystal with reversibly variable second harmonic generation

Michel Sliwa, Arnaud Spangenberg, Isabelle Malfant, Pascal G. Lacroix, Rémi Métivier, Robert B. Pansu, Keitaro Nakatani

Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires l'Ecole Normale Supérieure de Cachan
Laboratoire de Spectrochimie Infrarouge et Raman, Université des Sciences et Technologies de Lille, UMR-CNRS 8516
Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

N-(3,5-Ditert-butylsalicylidene)-2-aminopyridine (1) exhibits bulk second harmonic generation (SHG) activity (2 vs urea). X-ray diffraction measurements show a non-centrosymmetric structure (P3₂). Experimental data of polarization-dependent SHG match the theoretical calculations on the basis of the crystallographic data. 1 is also thermochromic in the crystalline state, and SHG at 120 K is 4 times as high as at room temperature. Comparison is made with the isostructural isomer, N-(3,5-ditert-butylsalicylidene) -4-aminopyridine (2), which exhibits reversible photoinduced SHG variations.

Original language	English
Pages (from-to)	4062-4068
Number of pages	7
Journal	Chemistry of Materials
Volume	20
Issue number	12
DOIs	https://doi.org/10.1021/cm800093a
Publication status	Published - 24 Jun 2008
Externally published	Yes

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title = "Structural, optical, and theoretical studies of a thermochromic organic crystal with reversibly variable second harmonic generation",

abstract = "N-(3,5-Ditert-butylsalicylidene)-2-aminopyridine (1) exhibits bulk second harmonic generation (SHG) activity (2 vs urea). X-ray diffraction measurements show a non-centrosymmetric structure (P32). Experimental data of polarization-dependent SHG match the theoretical calculations on the basis of the crystallographic data. 1 is also thermochromic in the crystalline state, and SHG at 120 K is 4 times as high as at room temperature. Comparison is made with the isostructural isomer, N-(3,5-ditert-butylsalicylidene) -4-aminopyridine (2), which exhibits reversible photoinduced SHG variations.",

author = "Michel Sliwa and Arnaud Spangenberg and Isabelle Malfant and Lacroix, \{Pascal G.\} and R{\'e}mi M{\'e}tivier and Pansu, \{Robert B.\} and Keitaro Nakatani",

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month = jun,

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doi = "10.1021/cm800093a",

language = "English",

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T1 - Structural, optical, and theoretical studies of a thermochromic organic crystal with reversibly variable second harmonic generation

AU - Sliwa, Michel

AU - Spangenberg, Arnaud

AU - Malfant, Isabelle

AU - Lacroix, Pascal G.

AU - Métivier, Rémi

AU - Pansu, Robert B.

AU - Nakatani, Keitaro

PY - 2008/6/24

Y1 - 2008/6/24

N2 - N-(3,5-Ditert-butylsalicylidene)-2-aminopyridine (1) exhibits bulk second harmonic generation (SHG) activity (2 vs urea). X-ray diffraction measurements show a non-centrosymmetric structure (P32). Experimental data of polarization-dependent SHG match the theoretical calculations on the basis of the crystallographic data. 1 is also thermochromic in the crystalline state, and SHG at 120 K is 4 times as high as at room temperature. Comparison is made with the isostructural isomer, N-(3,5-ditert-butylsalicylidene) -4-aminopyridine (2), which exhibits reversible photoinduced SHG variations.

AB - N-(3,5-Ditert-butylsalicylidene)-2-aminopyridine (1) exhibits bulk second harmonic generation (SHG) activity (2 vs urea). X-ray diffraction measurements show a non-centrosymmetric structure (P32). Experimental data of polarization-dependent SHG match the theoretical calculations on the basis of the crystallographic data. 1 is also thermochromic in the crystalline state, and SHG at 120 K is 4 times as high as at room temperature. Comparison is made with the isostructural isomer, N-(3,5-ditert-butylsalicylidene) -4-aminopyridine (2), which exhibits reversible photoinduced SHG variations.

U2 - 10.1021/cm800093a

DO - 10.1021/cm800093a

M3 - Article

AN - SCOPUS:47649130849

SN - 0897-4756

VL - 20

SP - 4062

EP - 4068

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 12

ER -

Structural, optical, and theoretical studies of a thermochromic organic crystal with reversibly variable second harmonic generation

Abstract

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