Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes: A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes

Duncan Carmichael; Xavier F. Le Goff; Eric Muller

doi:10.1039/b9nj00440h

Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes: A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes

Duncan Carmichael
, Xavier F. Le Goff
, Eric Muller

CNRS

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Convenient syntheses of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′-diphosphaferrocenes are described. Studies of the reactivity of alkali metal 3,4-dimethylphospholide, 2-ester-3,4-dimethyl phospholide and 2,5-diester-3,4-dimethylphospholide anions towards iron(ii) centres (as [Fe(AlCl₄)₂] or [Fe(MeCN)₆(BF₄)₂]) indicate that the corresponding 1,1′-diphosphaferrocenes are obtained without any complications resulting from redox chemistry at the iron centre.

Original language	English
Pages (from-to)	1341-1347
Number of pages	7
Journal	New Journal of Chemistry
Volume	34
Issue number	7
DOIs	https://doi.org/10.1039/b9nj00440h
Publication status	Published - 1 Jan 2010
Externally published	Yes

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@article{6e657ff7f93f405eb815d95d22f0f293,

title = "Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes: A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes",

abstract = "Convenient syntheses of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′-diphosphaferrocenes are described. Studies of the reactivity of alkali metal 3,4-dimethylphospholide, 2-ester-3,4-dimethyl phospholide and 2,5-diester-3,4-dimethylphospholide anions towards iron(ii) centres (as [Fe(AlCl4)2] or [Fe(MeCN)6(BF4)2]) indicate that the corresponding 1,1′-diphosphaferrocenes are obtained without any complications resulting from redox chemistry at the iron centre.",

author = "Duncan Carmichael and \{Le Goff\}, \{Xavier F.\} and Eric Muller",

year = "2010",

month = jan,

day = "1",

doi = "10.1039/b9nj00440h",

language = "English",

volume = "34",

pages = "1341--1347",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "7",

}

Carmichael, D, Le Goff, XF & Muller, E 2010, 'Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes: A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes', New Journal of Chemistry, vol. 34, no. 7, pp. 1341-1347. https://doi.org/10.1039/b9nj00440h

Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes: A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes. / Carmichael, Duncan; Le Goff, Xavier F.; Muller, Eric.
In: New Journal of Chemistry, Vol. 34, No. 7, 01.01.2010, p. 1341-1347.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Studies of how redox chemistry influences the synthesis of transition metal phosphametallocenes

T2 - A convenient synthesis of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′- diphosphaferrocenes

AU - Carmichael, Duncan

AU - Le Goff, Xavier F.

AU - Muller, Eric

PY - 2010/1/1

Y1 - 2010/1/1

N2 - Convenient syntheses of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′-diphosphaferrocenes are described. Studies of the reactivity of alkali metal 3,4-dimethylphospholide, 2-ester-3,4-dimethyl phospholide and 2,5-diester-3,4-dimethylphospholide anions towards iron(ii) centres (as [Fe(AlCl4)2] or [Fe(MeCN)6(BF4)2]) indicate that the corresponding 1,1′-diphosphaferrocenes are obtained without any complications resulting from redox chemistry at the iron centre.

AB - Convenient syntheses of 2,5-diester-substituted phosphametallocenes and 2,2′,5,5′-tetraester-substituted-1,1′-diphosphaferrocenes are described. Studies of the reactivity of alkali metal 3,4-dimethylphospholide, 2-ester-3,4-dimethyl phospholide and 2,5-diester-3,4-dimethylphospholide anions towards iron(ii) centres (as [Fe(AlCl4)2] or [Fe(MeCN)6(BF4)2]) indicate that the corresponding 1,1′-diphosphaferrocenes are obtained without any complications resulting from redox chemistry at the iron centre.

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DO - 10.1039/b9nj00440h

M3 - Article

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SN - 1144-0546

VL - 34

SP - 1341

EP - 1347

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 7

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