Study of new fluorine-containing epoxy resin for low dielectric constant

J. R. Lee; F. L. Jin; S. J. Park; J. M. Park

doi:10.1016/j.surfcoat.2003.10.111

Study of new fluorine-containing epoxy resin for low dielectric constant

J. R. Lee
, F. L. Jin
, S. J. Park
, J. M. Park

Research output: Contribution to journal › Article › peer-review

Abstract

In this work, the novel fluorine-containing epoxy resin, 2-diglycidylether of benzotrifluoride (DGEBTF), was prepared and the chemical structure of DGEBTF was confirmed by FT-IR, ¹³C NMR and ¹⁹F NMR spectroscopy. Also, the properties of DGEBTF/diaminodiphenyl methane (DDM) and well-known diglycidylether of bisphenol A (DGEBA)/DDM systems were investigated. As a result, the dielectric constant values of DGEBTF/DDM system were 15% lower than those of DGEBA/DDM system. The critical stress intensity factor and impact strength of DGEBTF/DDM and DGEBA/DDM systems were 5.63 MPa m^1/2, 50 kN/m² and 3.53 MPa m^1/2, 26 kN/m², respectively. The introduction of trifluoromethyl (CF₃) group into the chain of the epoxy resin resulted in improving the dielectric and mechanical properties and enormously lowered the T_g (105 °C) of the studied DGEBTF/DDM. It comes from the internal network change of cured resin.

Original language	English
Pages (from-to)	650-654
Number of pages	5
Journal	Surface and Coatings Technology
Volume	180-181
DOIs	https://doi.org/10.1016/j.surfcoat.2003.10.111
Publication status	Published - 1 Mar 2004
Externally published	Yes

Keywords

Activation energy
Critical stress intensity factor
Cure behavior
Dielectric constant
Epoxy resins
Fluorine

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10.1016/j.surfcoat.2003.10.111

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title = "Study of new fluorine-containing epoxy resin for low dielectric constant",

abstract = "In this work, the novel fluorine-containing epoxy resin, 2-diglycidylether of benzotrifluoride (DGEBTF), was prepared and the chemical structure of DGEBTF was confirmed by FT-IR, 13C NMR and 19F NMR spectroscopy. Also, the properties of DGEBTF/diaminodiphenyl methane (DDM) and well-known diglycidylether of bisphenol A (DGEBA)/DDM systems were investigated. As a result, the dielectric constant values of DGEBTF/DDM system were 15\% lower than those of DGEBA/DDM system. The critical stress intensity factor and impact strength of DGEBTF/DDM and DGEBA/DDM systems were 5.63 MPa m1/2, 50 kN/m2 and 3.53 MPa m1/2, 26 kN/m2, respectively. The introduction of trifluoromethyl (CF3) group into the chain of the epoxy resin resulted in improving the dielectric and mechanical properties and enormously lowered the Tg (105 °C) of the studied DGEBTF/DDM. It comes from the internal network change of cured resin.",

keywords = "Activation energy, Critical stress intensity factor, Cure behavior, Dielectric constant, Epoxy resins, Fluorine",

author = "Lee, \{J. R.\} and Jin, \{F. L.\} and Park, \{S. J.\} and Park, \{J. M.\}",

year = "2004",

month = mar,

day = "1",

doi = "10.1016/j.surfcoat.2003.10.111",

language = "English",

volume = "180-181",

pages = "650--654",

journal = "Surface and Coatings Technology",

issn = "0257-8972",

}

TY - JOUR

T1 - Study of new fluorine-containing epoxy resin for low dielectric constant

AU - Lee, J. R.

AU - Jin, F. L.

AU - Park, S. J.

AU - Park, J. M.

PY - 2004/3/1

Y1 - 2004/3/1

N2 - In this work, the novel fluorine-containing epoxy resin, 2-diglycidylether of benzotrifluoride (DGEBTF), was prepared and the chemical structure of DGEBTF was confirmed by FT-IR, 13C NMR and 19F NMR spectroscopy. Also, the properties of DGEBTF/diaminodiphenyl methane (DDM) and well-known diglycidylether of bisphenol A (DGEBA)/DDM systems were investigated. As a result, the dielectric constant values of DGEBTF/DDM system were 15% lower than those of DGEBA/DDM system. The critical stress intensity factor and impact strength of DGEBTF/DDM and DGEBA/DDM systems were 5.63 MPa m1/2, 50 kN/m2 and 3.53 MPa m1/2, 26 kN/m2, respectively. The introduction of trifluoromethyl (CF3) group into the chain of the epoxy resin resulted in improving the dielectric and mechanical properties and enormously lowered the Tg (105 °C) of the studied DGEBTF/DDM. It comes from the internal network change of cured resin.

AB - In this work, the novel fluorine-containing epoxy resin, 2-diglycidylether of benzotrifluoride (DGEBTF), was prepared and the chemical structure of DGEBTF was confirmed by FT-IR, 13C NMR and 19F NMR spectroscopy. Also, the properties of DGEBTF/diaminodiphenyl methane (DDM) and well-known diglycidylether of bisphenol A (DGEBA)/DDM systems were investigated. As a result, the dielectric constant values of DGEBTF/DDM system were 15% lower than those of DGEBA/DDM system. The critical stress intensity factor and impact strength of DGEBTF/DDM and DGEBA/DDM systems were 5.63 MPa m1/2, 50 kN/m2 and 3.53 MPa m1/2, 26 kN/m2, respectively. The introduction of trifluoromethyl (CF3) group into the chain of the epoxy resin resulted in improving the dielectric and mechanical properties and enormously lowered the Tg (105 °C) of the studied DGEBTF/DDM. It comes from the internal network change of cured resin.

KW - Activation energy

KW - Critical stress intensity factor

KW - Cure behavior

KW - Dielectric constant

KW - Epoxy resins

KW - Fluorine

UR - https://www.scopus.com/pages/publications/1842731922

U2 - 10.1016/j.surfcoat.2003.10.111

DO - 10.1016/j.surfcoat.2003.10.111

M3 - Article

AN - SCOPUS:1842731922

SN - 0257-8972

VL - 180-181

SP - 650

EP - 654

JO - Surface and Coatings Technology

JF - Surface and Coatings Technology

ER -

Study of new fluorine-containing epoxy resin for low dielectric constant

Abstract

Keywords

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