Sulfur chemistry in action. New perspectives for organic synthesis

Samir Z. Zard

doi:10.1080/10426507.2023.2173755

Sulfur chemistry in action. New perspectives for organic synthesis

Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Review article › peer-review

Abstract

The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates.

Original language	English
Pages (from-to)	456-465
Number of pages	10
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	198
Issue number	6
DOIs	https://doi.org/10.1080/10426507.2023.2173755
Publication status	Published - 1 Jan 2023
Externally published	Yes

Keywords

Alkene isomerization
boronates
ketones
radial addition
xanthates

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10.1080/10426507.2023.2173755

Cite this

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abstract = "The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates.",

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N2 - The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates.

AB - The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates.

KW - Alkene isomerization

KW - boronates

KW - ketones

KW - radial addition

KW - xanthates

UR - https://www.scopus.com/pages/publications/85147570440

U2 - 10.1080/10426507.2023.2173755

DO - 10.1080/10426507.2023.2173755

M3 - Review article

AN - SCOPUS:85147570440

SN - 1042-6507

VL - 198

SP - 456

EP - 465

JO - Phosphorus, Sulfur and Silicon and Related Elements

JF - Phosphorus, Sulfur and Silicon and Related Elements

IS - 6

ER -

Sulfur chemistry in action. New perspectives for organic synthesis

Abstract

Keywords

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