Synergistic reinforcing of poly(lactic acid) by poly(butylene adipate-co-terephthalate) and alumina nanoparticles

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Abstract

Biodegradable poly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blends and PLA/PBAT/Al2O3 nanocomposites were fabricated via solution blending. The influence of PBAT and Al2O3 content on the thermal stability, flexural properties, impact strength, and morphology of both the PLA/PBAT blends and the PLA/PBAT/Al2O3 nanocomposites were investigated. The impact strength of the PLA/PBAT/Al2O3 nanocomposites containing 5 wt% PBAT increased from 4.3 to 5.2 kJ/m2 when the Al2O3 content increased from 0 to 1 wt%. This represents a 62% increase compared to the impact strength of pristine PLA and a 20% increase compared to the impact strength of PLA/PBAT blends containing 5 wt% PBAT. Scanning electron microscopy imaging revealed that the Al2O3 nanoparticles in the PLA/PBAT/Al2O3 nanocomposites function as a compatibilizer to improve the interfacial interaction between the PBAT and the PLA matrix.

Original languageEnglish
Article number50250
JournalJournal of Applied Polymer Science
Volume138
Issue number16
DOIs
Publication statusPublished - 20 Apr 2021
Externally publishedYes

Keywords

  • biodegradable
  • biomaterials
  • biopolymers and renewable polymers

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