Synthesis and characterization of UV-curable acrylic resin containing fluorine groups

Soo Jin Park; Fan Long Jin

doi:10.1002/pi.1755

Synthesis and characterization of UV-curable acrylic resin containing fluorine groups

Soo Jin Park
, Fan Long Jin

Center for Convergent Research of Emerging Virus Infection

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A novel fluorine-containing acrylic resin, 4-trifluoromethylphenyl glycerol dimethacrylate (TPGD), was synthesized and the structure was characterized by FTIR, ¹³C NMR, ¹H NMR, and ¹⁹F NMR spectroscopy. The conversion of cure reaction, thermal stability, glass transition temperature (T_g), and electrical properties of the TPGD acrylic resin cured with UV radiation were investigated. The thermal stability and T_g of the UV-cured specimens show a maximum value at 1 wt% photoinitiator, due to the formation of advanced network structures. The cured specimens had a relatively low dielectric constant, attributed to the decreased deformation polarizability of segment motion in the fluorine-containing resin.

Original language	English
Pages (from-to)	705-709
Number of pages	5
Journal	Polymer International
Volume	54
Issue number	4
DOIs	https://doi.org/10.1002/pi.1755
Publication status	Published - 1 Apr 2005
Externally published	Yes

Keywords

Acrylic resin
Dielectric constant
Fluorine
Glass transition temperature
Thermal stability

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10.1002/pi.1755

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title = "Synthesis and characterization of UV-curable acrylic resin containing fluorine groups",

abstract = "A novel fluorine-containing acrylic resin, 4-trifluoromethylphenyl glycerol dimethacrylate (TPGD), was synthesized and the structure was characterized by FTIR, 13C NMR, 1H NMR, and 19F NMR spectroscopy. The conversion of cure reaction, thermal stability, glass transition temperature (Tg), and electrical properties of the TPGD acrylic resin cured with UV radiation were investigated. The thermal stability and Tg of the UV-cured specimens show a maximum value at 1 wt\% photoinitiator, due to the formation of advanced network structures. The cured specimens had a relatively low dielectric constant, attributed to the decreased deformation polarizability of segment motion in the fluorine-containing resin.",

keywords = "Acrylic resin, Dielectric constant, Fluorine, Glass transition temperature, Thermal stability",

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year = "2005",

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T1 - Synthesis and characterization of UV-curable acrylic resin containing fluorine groups

AU - Park, Soo Jin

AU - Jin, Fan Long

PY - 2005/4/1

Y1 - 2005/4/1

N2 - A novel fluorine-containing acrylic resin, 4-trifluoromethylphenyl glycerol dimethacrylate (TPGD), was synthesized and the structure was characterized by FTIR, 13C NMR, 1H NMR, and 19F NMR spectroscopy. The conversion of cure reaction, thermal stability, glass transition temperature (Tg), and electrical properties of the TPGD acrylic resin cured with UV radiation were investigated. The thermal stability and Tg of the UV-cured specimens show a maximum value at 1 wt% photoinitiator, due to the formation of advanced network structures. The cured specimens had a relatively low dielectric constant, attributed to the decreased deformation polarizability of segment motion in the fluorine-containing resin.

AB - A novel fluorine-containing acrylic resin, 4-trifluoromethylphenyl glycerol dimethacrylate (TPGD), was synthesized and the structure was characterized by FTIR, 13C NMR, 1H NMR, and 19F NMR spectroscopy. The conversion of cure reaction, thermal stability, glass transition temperature (Tg), and electrical properties of the TPGD acrylic resin cured with UV radiation were investigated. The thermal stability and Tg of the UV-cured specimens show a maximum value at 1 wt% photoinitiator, due to the formation of advanced network structures. The cured specimens had a relatively low dielectric constant, attributed to the decreased deformation polarizability of segment motion in the fluorine-containing resin.

KW - Acrylic resin

KW - Dielectric constant

KW - Fluorine

KW - Glass transition temperature

KW - Thermal stability

UR - https://www.scopus.com/pages/publications/14944364710

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DO - 10.1002/pi.1755

M3 - Article

AN - SCOPUS:14944364710

SN - 0959-8103

VL - 54

SP - 705

EP - 709

JO - Polymer International

JF - Polymer International

IS - 4

ER -

Synthesis and characterization of UV-curable acrylic resin containing fluorine groups

Abstract

Keywords

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