Synthesis and characterizations of YVO4: Eu colloids

A. Huignard; V. Buissette; G. Laurent; T. Gacoin; J. P. Boilot

doi:10.1021/cm011263a

Synthesis and characterizations of YVO₄: Eu colloids

A. Huignard
, V. Buissette
, G. Laurent
, T. Gacoin
, J. P. Boilot

Research output: Contribution to journal › Article › peer-review

Abstract

We present a new process for the synthesis of colloidal europium-doped yttrium vanadate with a particle diameter of about 10 nm. Nanocrystals are produced by precipitation of citrate complexes of rare-earth salts with sodium orthovanadate. NMR and IR studies show that the interaction between citrate ligands and lanthanide ions limits the growth of particles and ensures the stability of the colloidal solutions through electrostatic and steric repulsions. The optimized process leads to stable and highly concentrated transparent colloidal solutions in water (up to 400 g·L^-1).

Original language	English
Pages (from-to)	2264-2269
Number of pages	6
Journal	Chemistry of Materials
Volume	14
Issue number	5
DOIs	https://doi.org/10.1021/cm011263a
Publication status	Published - 10 Jun 2002

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10.1021/cm011263a

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abstract = "We present a new process for the synthesis of colloidal europium-doped yttrium vanadate with a particle diameter of about 10 nm. Nanocrystals are produced by precipitation of citrate complexes of rare-earth salts with sodium orthovanadate. NMR and IR studies show that the interaction between citrate ligands and lanthanide ions limits the growth of particles and ensures the stability of the colloidal solutions through electrostatic and steric repulsions. The optimized process leads to stable and highly concentrated transparent colloidal solutions in water (up to 400 g·L-1).",

author = "A. Huignard and V. Buissette and G. Laurent and T. Gacoin and Boilot, \{J. P.\}",

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T1 - Synthesis and characterizations of YVO4

T2 - Eu colloids

AU - Huignard, A.

AU - Buissette, V.

AU - Laurent, G.

AU - Gacoin, T.

AU - Boilot, J. P.

PY - 2002/6/10

Y1 - 2002/6/10

N2 - We present a new process for the synthesis of colloidal europium-doped yttrium vanadate with a particle diameter of about 10 nm. Nanocrystals are produced by precipitation of citrate complexes of rare-earth salts with sodium orthovanadate. NMR and IR studies show that the interaction between citrate ligands and lanthanide ions limits the growth of particles and ensures the stability of the colloidal solutions through electrostatic and steric repulsions. The optimized process leads to stable and highly concentrated transparent colloidal solutions in water (up to 400 g·L-1).

AB - We present a new process for the synthesis of colloidal europium-doped yttrium vanadate with a particle diameter of about 10 nm. Nanocrystals are produced by precipitation of citrate complexes of rare-earth salts with sodium orthovanadate. NMR and IR studies show that the interaction between citrate ligands and lanthanide ions limits the growth of particles and ensures the stability of the colloidal solutions through electrostatic and steric repulsions. The optimized process leads to stable and highly concentrated transparent colloidal solutions in water (up to 400 g·L-1).

U2 - 10.1021/cm011263a

DO - 10.1021/cm011263a

M3 - Article

AN - SCOPUS:0036265312

SN - 0897-4756

VL - 14

SP - 2264

EP - 2269

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 5

ER -

Synthesis and characterizations of YVO4: Eu colloids

Abstract

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Synthesis and characterizations of YVO₄: Eu colloids