Synthesis and thermal properties of epoxidized vegetable oil

Soo Jin Park; Fan Long Jin; Jae Rock Lee

doi:10.1002/marc.200300191

Synthesis and thermal properties of epoxidized vegetable oil

Soo Jin Park
, Fan Long Jin
, Jae Rock Lee

Center for Convergent Research of Emerging Virus Infection

Research output: Contribution to journal › Article › peer-review

Abstract

The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher T_g and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

Original language	English
Pages (from-to)	724-727
Number of pages	4
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	6
DOIs	https://doi.org/10.1002/marc.200300191
Publication status	Published - 19 Mar 2004
Externally published	Yes

Keywords

Catalysts
Cationic polymerization
Crosslinking
Density
Thermal properties

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10.1002/marc.200300191

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title = "Synthesis and thermal properties of epoxidized vegetable oil",

abstract = "The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.",

keywords = "Catalysts, Cationic polymerization, Crosslinking, Density, Thermal properties",

author = "Park, \{Soo Jin\} and Jin, \{Fan Long\} and Lee, \{Jae Rock\}",

year = "2004",

month = mar,

day = "19",

doi = "10.1002/marc.200300191",

language = "English",

volume = "25",

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journal = "Macromolecular Rapid Communications",

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TY - JOUR

T1 - Synthesis and thermal properties of epoxidized vegetable oil

AU - Park, Soo Jin

AU - Jin, Fan Long

AU - Lee, Jae Rock

PY - 2004/3/19

Y1 - 2004/3/19

N2 - The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

AB - The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst. N-benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.

KW - Catalysts

KW - Cationic polymerization

KW - Crosslinking

KW - Density

KW - Thermal properties

UR - https://www.scopus.com/pages/publications/4544386859

U2 - 10.1002/marc.200300191

DO - 10.1002/marc.200300191

M3 - Article

AN - SCOPUS:4544386859

SN - 1022-1336

VL - 25

SP - 724

EP - 727

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 6

ER -

Synthesis and thermal properties of epoxidized vegetable oil

Abstract

Keywords

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