Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N, N′,N′-tetramethylethylenediamine)

Robert L. Halbach; Grégory Nocton; Richard A. Andersen

doi:10.1039/c2dt30810j

Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N, N′,N′-tetramethylethylenediamine)

Robert L. Halbach
, Grégory Nocton
, Richard A. Andersen

University of California, Berkeley

Research output: Contribution to journal › Article › peer-review

Abstract

Although several ruthenium complexes of the type Ru(acac) ₂(L) _x, where x is 1 for a bidentate or 2 for a monodentate ligand, are known, the tmed complex is conspicuously absent. This article describes the synthesis of this complex from trans-RuCl ₂(tmed) ₂, acetylacetone, and triethylamine in toluene. A new synthesis of trans-RuCl ₂(tmed) ₂ is also described. Some physical properties and the X-ray crystal structure of Ru(acac) ₂(tmed) are provided.

Original language	English
Pages (from-to)	8809-8812
Number of pages	4
Journal	Dalton Transactions
Volume	41
Issue number	29
DOIs	https://doi.org/10.1039/c2dt30810j
Publication status	Published - 7 Aug 2012
Externally published	Yes

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title = "Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N, N′,N′-tetramethylethylenediamine)",

abstract = "Although several ruthenium complexes of the type Ru(acac) 2(L) x, where x is 1 for a bidentate or 2 for a monodentate ligand, are known, the tmed complex is conspicuously absent. This article describes the synthesis of this complex from trans-RuCl 2(tmed) 2, acetylacetone, and triethylamine in toluene. A new synthesis of trans-RuCl 2(tmed) 2 is also described. Some physical properties and the X-ray crystal structure of Ru(acac) 2(tmed) are provided.",

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T1 - Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N, N′,N′-tetramethylethylenediamine)

AU - Halbach, Robert L.

AU - Nocton, Grégory

AU - Andersen, Richard A.

PY - 2012/8/7

Y1 - 2012/8/7

N2 - Although several ruthenium complexes of the type Ru(acac) 2(L) x, where x is 1 for a bidentate or 2 for a monodentate ligand, are known, the tmed complex is conspicuously absent. This article describes the synthesis of this complex from trans-RuCl 2(tmed) 2, acetylacetone, and triethylamine in toluene. A new synthesis of trans-RuCl 2(tmed) 2 is also described. Some physical properties and the X-ray crystal structure of Ru(acac) 2(tmed) are provided.

AB - Although several ruthenium complexes of the type Ru(acac) 2(L) x, where x is 1 for a bidentate or 2 for a monodentate ligand, are known, the tmed complex is conspicuously absent. This article describes the synthesis of this complex from trans-RuCl 2(tmed) 2, acetylacetone, and triethylamine in toluene. A new synthesis of trans-RuCl 2(tmed) 2 is also described. Some physical properties and the X-ray crystal structure of Ru(acac) 2(tmed) are provided.

U2 - 10.1039/c2dt30810j

DO - 10.1039/c2dt30810j

M3 - Article

AN - SCOPUS:84863702221

SN - 1477-9226

VL - 41

SP - 8809

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 29

ER -

Synthesis and X-ray structure of ruthenium bis(acetylacetonate)(N,N, N′,N′-tetramethylethylenediamine)

Abstract

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