Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics

Wei Jiang; Fan Long Jin; Soo Jin Park

doi:10.1016/j.jiec.2015.01.010

Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics

Wei Jiang
, Fan Long Jin
, Soo Jin Park

Research output: Contribution to journal › Article › peer-review

Abstract

A novel phosphorus-nitrogen-containing intumescent flame retardant (IFR), ditrimethylolpropane di-N-hydroxyethyl phosphoramide (DDP), was successfully synthesized and used as a flame retardant for various fabrics. The chemical structure of DDP was characterized using FT-IR, ¹H NMR, ³¹P NMR, and elemental analysis. The thermal property of DDP was investigated by thermogravimetric analysis. The effect of DDP on the flame-retardant properties of fabrics was evaluated by measurement of the burning length. The optimal synthesis conditions for DDP were determined. DDP showed high flame retardancy when applied to nylon and moderate flame retardancy when applied to cotton and polyester.

Original language	English
Pages (from-to)	40-43
Number of pages	4
Journal	Journal of Industrial and Engineering Chemistry
Volume	27
DOIs	https://doi.org/10.1016/j.jiec.2015.01.010
Publication status	Published - 25 Jul 2015
Externally published	Yes

Keywords

Fabrics
Flame-retardant properties
Intumescent flame retardant
Nitrogen
Phosphorus

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10.1016/j.jiec.2015.01.010

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@article{e6399cd2d2c84ac49bef98267e1f3b90,

title = "Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics",

abstract = "A novel phosphorus-nitrogen-containing intumescent flame retardant (IFR), ditrimethylolpropane di-N-hydroxyethyl phosphoramide (DDP), was successfully synthesized and used as a flame retardant for various fabrics. The chemical structure of DDP was characterized using FT-IR, 1H NMR, 31P NMR, and elemental analysis. The thermal property of DDP was investigated by thermogravimetric analysis. The effect of DDP on the flame-retardant properties of fabrics was evaluated by measurement of the burning length. The optimal synthesis conditions for DDP were determined. DDP showed high flame retardancy when applied to nylon and moderate flame retardancy when applied to cotton and polyester.",

keywords = "Fabrics, Flame-retardant properties, Intumescent flame retardant, Nitrogen, Phosphorus",

author = "Wei Jiang and Jin, \{Fan Long\} and Park, \{Soo Jin\}",

note = "Publisher Copyright: {\textcopyright} 2015 The Korean Society of Industrial and Engineering Chemistry.",

year = "2015",

month = jul,

day = "25",

doi = "10.1016/j.jiec.2015.01.010",

language = "English",

volume = "27",

pages = "40--43",

journal = "Journal of Industrial and Engineering Chemistry",

issn = "1226-086X",

}

TY - JOUR

T1 - Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics

AU - Jiang, Wei

AU - Jin, Fan Long

AU - Park, Soo Jin

PY - 2015/7/25

Y1 - 2015/7/25

N2 - A novel phosphorus-nitrogen-containing intumescent flame retardant (IFR), ditrimethylolpropane di-N-hydroxyethyl phosphoramide (DDP), was successfully synthesized and used as a flame retardant for various fabrics. The chemical structure of DDP was characterized using FT-IR, 1H NMR, 31P NMR, and elemental analysis. The thermal property of DDP was investigated by thermogravimetric analysis. The effect of DDP on the flame-retardant properties of fabrics was evaluated by measurement of the burning length. The optimal synthesis conditions for DDP were determined. DDP showed high flame retardancy when applied to nylon and moderate flame retardancy when applied to cotton and polyester.

AB - A novel phosphorus-nitrogen-containing intumescent flame retardant (IFR), ditrimethylolpropane di-N-hydroxyethyl phosphoramide (DDP), was successfully synthesized and used as a flame retardant for various fabrics. The chemical structure of DDP was characterized using FT-IR, 1H NMR, 31P NMR, and elemental analysis. The thermal property of DDP was investigated by thermogravimetric analysis. The effect of DDP on the flame-retardant properties of fabrics was evaluated by measurement of the burning length. The optimal synthesis conditions for DDP were determined. DDP showed high flame retardancy when applied to nylon and moderate flame retardancy when applied to cotton and polyester.

KW - Fabrics

KW - Flame-retardant properties

KW - Intumescent flame retardant

KW - Nitrogen

KW - Phosphorus

UR - https://www.scopus.com/pages/publications/84930818177

U2 - 10.1016/j.jiec.2015.01.010

DO - 10.1016/j.jiec.2015.01.010

M3 - Article

AN - SCOPUS:84930818177

SN - 1226-086X

VL - 27

SP - 40

EP - 43

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

ER -

Synthesis of a novel phosphorus-nitrogen-containing intumescent flame retardant and its application to fabrics

Abstract

Keywords

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