Synthesis of Mn2+ doped CdS nanocrystals embedded in a sol-gel silica matrix: characterization of the luminescence activator

G. Counio; S. Esnouf; T. Gacoin; P. Barboux; A. Hofstaetter; J. P. Boilot

Synthesis of Mn²⁺ doped CdS nanocrystals embedded in a sol-gel silica matrix: characterization of the luminescence activator

G. Counio, S. Esnouf, T. Gacoin, P. Barboux, A. Hofstaetter, J. P. Boilot

Lab de Physique de la Mateire

Research output: Contribution to journal › Conference article › peer-review

Abstract

Mn²⁺-doped CdS nanocrystals (1.2 to 2.4 nm in diameter) embedded in organic-inorganic silica xerogels have been synthesized. Extensive studies (EXAFS, ESR and ENDOR) allow us to localize the ions responsible for the bright luminescence observed in such materials (quantum yield of 7%). The average number of Mn²⁺ per nanocrystal is in the 0.2-0.8 range, and the emission arises from an energy transfer from surface trapped carriers to Mn²⁺ ions.

Original language	English
Pages (from-to)	311-316
Number of pages	6
Journal	Materials Research Society Symposium - Proceedings
Volume	452
Publication status	Published - 1 Jan 1997
Externally published	Yes
Event	Proceedings of the 1996 MRS Fall Meeting - Boston, MA, USA Duration: 2 Dec 1996 → 6 Dec 1996

Cite this

@article{25014a4a338c4612b5154246fa17108e,

title = "Synthesis of Mn2+ doped CdS nanocrystals embedded in a sol-gel silica matrix: characterization of the luminescence activator",

abstract = "Mn2+-doped CdS nanocrystals (1.2 to 2.4 nm in diameter) embedded in organic-inorganic silica xerogels have been synthesized. Extensive studies (EXAFS, ESR and ENDOR) allow us to localize the ions responsible for the bright luminescence observed in such materials (quantum yield of 7\%). The average number of Mn2+ per nanocrystal is in the 0.2-0.8 range, and the emission arises from an energy transfer from surface trapped carriers to Mn2+ ions.",

author = "G. Counio and S. Esnouf and T. Gacoin and P. Barboux and A. Hofstaetter and Boilot, \{J. P.\}",

year = "1997",

month = jan,

day = "1",

language = "English",

volume = "452",

pages = "311--316",

journal = "Materials Research Society Symposium - Proceedings",

issn = "0272-9172",

note = "Proceedings of the 1996 MRS Fall Meeting ; Conference date: 02-12-1996 Through 06-12-1996",

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TY - JOUR

T1 - Synthesis of Mn2+ doped CdS nanocrystals embedded in a sol-gel silica matrix

T2 - Proceedings of the 1996 MRS Fall Meeting

AU - Counio, G.

AU - Esnouf, S.

AU - Gacoin, T.

AU - Barboux, P.

AU - Hofstaetter, A.

AU - Boilot, J. P.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Mn2+-doped CdS nanocrystals (1.2 to 2.4 nm in diameter) embedded in organic-inorganic silica xerogels have been synthesized. Extensive studies (EXAFS, ESR and ENDOR) allow us to localize the ions responsible for the bright luminescence observed in such materials (quantum yield of 7%). The average number of Mn2+ per nanocrystal is in the 0.2-0.8 range, and the emission arises from an energy transfer from surface trapped carriers to Mn2+ ions.

AB - Mn2+-doped CdS nanocrystals (1.2 to 2.4 nm in diameter) embedded in organic-inorganic silica xerogels have been synthesized. Extensive studies (EXAFS, ESR and ENDOR) allow us to localize the ions responsible for the bright luminescence observed in such materials (quantum yield of 7%). The average number of Mn2+ per nanocrystal is in the 0.2-0.8 range, and the emission arises from an energy transfer from surface trapped carriers to Mn2+ ions.

M3 - Conference article

AN - SCOPUS:0030705096

SN - 0272-9172

VL - 452

SP - 311

EP - 316

JO - Materials Research Society Symposium - Proceedings

JF - Materials Research Society Symposium - Proceedings

Y2 - 2 December 1996 through 6 December 1996

ER -

Synthesis of Mn2+ doped CdS nanocrystals embedded in a sol-gel silica matrix: characterization of the luminescence activator

Abstract

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Synthesis of Mn²⁺ doped CdS nanocrystals embedded in a sol-gel silica matrix: characterization of the luminescence activator