Synthesis, structure and protonic conduction of BaSn0.875M 0.125O3-δ (M = Sc, Y, in and Gd)

Yanzhong Wang; Anthony Chesnaud; Emile Bevillon; Jinlong Yang; Guilhem Dezanneau

doi:10.1016/j.ijhydene.2011.03.105

Synthesis, structure and protonic conduction of BaSn_0.875M _0.125O_3-δ (M = Sc, Y, in and Gd)

Yanzhong Wang, Anthony Chesnaud, Emile Bevillon, Jinlong Yang, Guilhem Dezanneau

Research output: Contribution to journal › Article › peer-review

Abstract

The acceptor-substituted BaSn_0.875M_0.125O _3-δ (M = Sc, In, Y, and Gd) proton conductors were prepared by a wet chemical method. The effects of dopant nature on the structure, hydration energy and proton conduction have been investigated. Analysis of XRD data showed that all compounds present a cubic perovskite structure (space group: Pm3-m). Thermogravimetry analysis showed that the significant mass of water was gained in wet Ar during measurements, and the most negative hydration energy is observed for Sc-substituted BaSnO₃ (-86 kJ/mol). However, Y-substituted BaSnO₃ exhibits the highest proton conductivity at low temperature under wet Ar, such as the total conductivity is 4.8 × 10 ^-4 S/cm at 600 °C.

Original language	English
Pages (from-to)	7688-7695
Number of pages	8
Journal	International Journal of Hydrogen Energy
Volume	36
Issue number	13
DOIs	https://doi.org/10.1016/j.ijhydene.2011.03.105
Publication status	Published - 1 Jul 2011
Externally published	Yes

Keywords

BaSnO
Hydration energy
Lattice parameters
Perovskite structure
Proton conductor

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This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.ijhydene.2011.03.105

Cite this

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title = "Synthesis, structure and protonic conduction of BaSn0.875M 0.125O3-δ (M = Sc, Y, in and Gd)",

abstract = "The acceptor-substituted BaSn0.875M0.125O 3-δ (M = Sc, In, Y, and Gd) proton conductors were prepared by a wet chemical method. The effects of dopant nature on the structure, hydration energy and proton conduction have been investigated. Analysis of XRD data showed that all compounds present a cubic perovskite structure (space group: Pm3-m). Thermogravimetry analysis showed that the significant mass of water was gained in wet Ar during measurements, and the most negative hydration energy is observed for Sc-substituted BaSnO3 (-86 kJ/mol). However, Y-substituted BaSnO3 exhibits the highest proton conductivity at low temperature under wet Ar, such as the total conductivity is 4.8 × 10 -4 S/cm at 600 °C.",

keywords = "BaSnO, Hydration energy, Lattice parameters, Perovskite structure, Proton conductor",

author = "Yanzhong Wang and Anthony Chesnaud and Emile Bevillon and Jinlong Yang and Guilhem Dezanneau",

year = "2011",

month = jul,

day = "1",

doi = "10.1016/j.ijhydene.2011.03.105",

language = "English",

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journal = "International Journal of Hydrogen Energy",

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TY - JOUR

T1 - Synthesis, structure and protonic conduction of BaSn0.875M 0.125O3-δ (M = Sc, Y, in and Gd)

AU - Wang, Yanzhong

AU - Chesnaud, Anthony

AU - Bevillon, Emile

AU - Yang, Jinlong

AU - Dezanneau, Guilhem

PY - 2011/7/1

Y1 - 2011/7/1

N2 - The acceptor-substituted BaSn0.875M0.125O 3-δ (M = Sc, In, Y, and Gd) proton conductors were prepared by a wet chemical method. The effects of dopant nature on the structure, hydration energy and proton conduction have been investigated. Analysis of XRD data showed that all compounds present a cubic perovskite structure (space group: Pm3-m). Thermogravimetry analysis showed that the significant mass of water was gained in wet Ar during measurements, and the most negative hydration energy is observed for Sc-substituted BaSnO3 (-86 kJ/mol). However, Y-substituted BaSnO3 exhibits the highest proton conductivity at low temperature under wet Ar, such as the total conductivity is 4.8 × 10 -4 S/cm at 600 °C.

AB - The acceptor-substituted BaSn0.875M0.125O 3-δ (M = Sc, In, Y, and Gd) proton conductors were prepared by a wet chemical method. The effects of dopant nature on the structure, hydration energy and proton conduction have been investigated. Analysis of XRD data showed that all compounds present a cubic perovskite structure (space group: Pm3-m). Thermogravimetry analysis showed that the significant mass of water was gained in wet Ar during measurements, and the most negative hydration energy is observed for Sc-substituted BaSnO3 (-86 kJ/mol). However, Y-substituted BaSnO3 exhibits the highest proton conductivity at low temperature under wet Ar, such as the total conductivity is 4.8 × 10 -4 S/cm at 600 °C.

KW - BaSnO

KW - Hydration energy

KW - Lattice parameters

KW - Perovskite structure

KW - Proton conductor

U2 - 10.1016/j.ijhydene.2011.03.105

DO - 10.1016/j.ijhydene.2011.03.105

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JF - International Journal of Hydrogen Energy

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ER -