Synthetic routes to β-lactams. Some unexpected hydrogen atom transfer reactions

Laurent Boiteau; Jean Boivin; Béatrice Quiclet-Sire; Jean Baptiste Saunier; Samir Z. Zard

doi:10.1016/S0040-4020(97)10417-3

Synthetic routes to β-lactams. Some unexpected hydrogen atom transfer reactions

Laurent Boiteau
, Jean Boivin
, Béatrice Quiclet-Sire
, Jean Baptiste Saunier
, Samir Z. Zard

Laboratoire de Synthèse Organique
Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Appropriately substituted xanthate derivatives of N-ethenyl acetamides undergo radical cyclisation to give β-lactams with transfer of the xanthate group. In one case, a cascade of unexpected and unusual hydrogen transfer reactions occurred.

Original language	English
Pages (from-to)	2087-2098
Number of pages	12
Journal	Tetrahedron
Volume	54
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4020(97)10417-3
Publication status	Published - 5 Mar 1998

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@article{02003db2c5e048a4882798bc40c4a73d,

title = "Synthetic routes to β-lactams. Some unexpected hydrogen atom transfer reactions",

abstract = "Appropriately substituted xanthate derivatives of N-ethenyl acetamides undergo radical cyclisation to give β-lactams with transfer of the xanthate group. In one case, a cascade of unexpected and unusual hydrogen transfer reactions occurred.",

author = "Laurent Boiteau and Jean Boivin and B{\'e}atrice Quiclet-Sire and Saunier, \{Jean Baptiste\} and Zard, \{Samir Z.\}",

year = "1998",

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T1 - Synthetic routes to β-lactams. Some unexpected hydrogen atom transfer reactions

AU - Boiteau, Laurent

AU - Boivin, Jean

AU - Quiclet-Sire, Béatrice

AU - Saunier, Jean Baptiste

AU - Zard, Samir Z.

PY - 1998/3/5

Y1 - 1998/3/5

N2 - Appropriately substituted xanthate derivatives of N-ethenyl acetamides undergo radical cyclisation to give β-lactams with transfer of the xanthate group. In one case, a cascade of unexpected and unusual hydrogen transfer reactions occurred.

AB - Appropriately substituted xanthate derivatives of N-ethenyl acetamides undergo radical cyclisation to give β-lactams with transfer of the xanthate group. In one case, a cascade of unexpected and unusual hydrogen transfer reactions occurred.

U2 - 10.1016/S0040-4020(97)10417-3

DO - 10.1016/S0040-4020(97)10417-3

M3 - Article

AN - SCOPUS:0032485358

SN - 0040-4020

VL - 54

SP - 2087

EP - 2098

JO - Tetrahedron

JF - Tetrahedron

IS - 10

ER -

Synthetic routes to β-lactams. Some unexpected hydrogen atom transfer reactions

Abstract

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