The genesis of the reversible radical addition-fragmentation-transfer of thiocarbonylthio derivatives from the Barton-McCombie deoxygenation: A brief account and some mechanistic observations

Samir Z. Zard

doi:10.1071/CH06263

The genesis of the reversible radical addition-fragmentation-transfer of thiocarbonylthio derivatives from the Barton-McCombie deoxygenation: A brief account and some mechanistic observations

Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

The observations and reasoning leading to the discovery of the degenerative transfer of xanthates and related thiocarbonylthio derivatives are briefly described. A few synthetic applications are presented, and the consequences on the emergence of the RAFT and MADIX polymerization technologies as well as some mechanistic aspects are briefly discussed.

Original language	English
Pages (from-to)	663-668
Number of pages	6
Journal	Australian Journal of Chemistry
Volume	59
Issue number	10
DOIs	https://doi.org/10.1071/CH06263
Publication status	Published - 1 Jan 2006
Externally published	Yes

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abstract = "The observations and reasoning leading to the discovery of the degenerative transfer of xanthates and related thiocarbonylthio derivatives are briefly described. A few synthetic applications are presented, and the consequences on the emergence of the RAFT and MADIX polymerization technologies as well as some mechanistic aspects are briefly discussed.",

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AB - The observations and reasoning leading to the discovery of the degenerative transfer of xanthates and related thiocarbonylthio derivatives are briefly described. A few synthetic applications are presented, and the consequences on the emergence of the RAFT and MADIX polymerization technologies as well as some mechanistic aspects are briefly discussed.

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The genesis of the reversible radical addition-fragmentation-transfer of thiocarbonylthio derivatives from the Barton-McCombie deoxygenation: A brief account and some mechanistic observations

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