The theoretical description of an asymmetric, nonresonant charge transfer process; Li + Na+ ⇌ Li+ + Na the two-state approximation

Carl F. Melius; William A. Goddard

doi:10.1016/0009-2614(72)80364-6

The theoretical description of an asymmetric, nonresonant charge transfer process; Li + Na⁺ ⇌ Li⁺ + Na the two-state approximation

Carl F. Melius
, William A. Goddard

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The charge transfer process for the collision Li + Na⁺ ⇌ Li⁺ + Na has been studied theoretically by a two-state, impact parameter approach using molecular wavefunctions. Including the coupling term 〈ψ₁{divides}∂/∂R{divides}ψ₂〉 due to the breakdown of the Born-Oppenheimer approximation, we obtain total charge transfer cross sections in good agreement with experimental results.

Original language	English
Pages (from-to)	524-529
Number of pages	6
Journal	Chemical Physics Letters
Volume	15
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(72)80364-6
Publication status	Published - 1 Sept 1972
Externally published	Yes

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title = "The theoretical description of an asymmetric, nonresonant charge transfer process; Li + Na+ ⇌ Li+ + Na the two-state approximation",

abstract = "The charge transfer process for the collision Li + Na+ ⇌ Li+ + Na has been studied theoretically by a two-state, impact parameter approach using molecular wavefunctions. Including the coupling term 〈ψ1\{divides\}∂/∂R\{divides\}ψ2〉 due to the breakdown of the Born-Oppenheimer approximation, we obtain total charge transfer cross sections in good agreement with experimental results.",

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AU - Goddard, William A.

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N2 - The charge transfer process for the collision Li + Na+ ⇌ Li+ + Na has been studied theoretically by a two-state, impact parameter approach using molecular wavefunctions. Including the coupling term 〈ψ1{divides}∂/∂R{divides}ψ2〉 due to the breakdown of the Born-Oppenheimer approximation, we obtain total charge transfer cross sections in good agreement with experimental results.

AB - The charge transfer process for the collision Li + Na+ ⇌ Li+ + Na has been studied theoretically by a two-state, impact parameter approach using molecular wavefunctions. Including the coupling term 〈ψ1{divides}∂/∂R{divides}ψ2〉 due to the breakdown of the Born-Oppenheimer approximation, we obtain total charge transfer cross sections in good agreement with experimental results.

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DO - 10.1016/0009-2614(72)80364-6

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

The theoretical description of an asymmetric, nonresonant charge transfer process; Li + Na⁺ ⇌ Li⁺ + Na the two-state approximation

Abstract

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