The xanthate route to all-carbon quaternary centers

Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1007/s11426-019-9587-x

The xanthate route to all-carbon quaternary centers

Béatrice Quiclet-Sire
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Review article › peer-review

Abstract

This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

Original language	English
Pages (from-to)	1450-1462
Number of pages	13
Journal	Science China Chemistry
Volume	62
Issue number	11
DOIs	https://doi.org/10.1007/s11426-019-9587-x
Publication status	Published - 1 Nov 2019
Externally published	Yes

Keywords

cyclization
quaternary centers
radical addition
tandem reactions
xanthates

Access to Document

10.1007/s11426-019-9587-x

Cite this

@article{124886397b17481da7d1f0afbd9243bb,

title = "The xanthate route to all-carbon quaternary centers",

abstract = "This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.",

keywords = "cyclization, quaternary centers, radical addition, tandem reactions, xanthates",

author = "B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} 2019, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2019",

month = nov,

day = "1",

doi = "10.1007/s11426-019-9587-x",

language = "English",

volume = "62",

pages = "1450--1462",

journal = "Science China Chemistry",

issn = "1674-7291",

number = "11",

}

TY - JOUR

T1 - The xanthate route to all-carbon quaternary centers

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

AB - This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates. It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra- and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.

KW - cyclization

KW - quaternary centers

KW - radical addition

KW - tandem reactions

KW - xanthates

U2 - 10.1007/s11426-019-9587-x

DO - 10.1007/s11426-019-9587-x

M3 - Review article

AN - SCOPUS:85074088768

SN - 1674-7291

VL - 62

SP - 1450

EP - 1462

JO - Science China Chemistry

JF - Science China Chemistry

IS - 11

ER -

The xanthate route to all-carbon quaternary centers

Abstract

Keywords

Access to Document

Fingerprint

Cite this