Abstract
Mumm's the word: The title reaction can be performed by the addition of isocyanides to benzenediazonium salts in the presence of sodium or potassium carboxylates. The reaction involves nitrilium intermediates which may be trapped by water or carboxylic acids to form amides and imides, respectively, after Mumm rearrangement.
| Original language | English |
|---|---|
| Pages (from-to) | 7194-7197 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 28 |
| DOIs | |
| Publication status | Published - 8 Jul 2013 |
| Externally published | Yes |
Keywords
- arylation
- isocyanides
- reaction mechanisms
- rearrangement
- synthetic methods