Titanium oxide synthesis in aqueous medium

M. Koelsch; S. Cassaignon; J. F. Guillemoles; J. P. Jolivet

Titanium oxide synthesis in aqueous medium

M. Koelsch
, S. Cassaignon
, J. F. Guillemoles
, J. P. Jolivet

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Nanometric particles of titania, anatase, brookite and rutile polymorphs, were synthesized by thermohydrolysis of TiCl₄ in aqueous medium. The control of the medium acidity allows the control of the crystalline structure, the size and the morphology of particles. In concentrated HCl (≥ 1mol.L ^-1) solutions, the Cl/Ti molar ratio seems to be the key factor to determine the relative proportions of brookite and rutile as well as the particle size. Nanoparticles of anatase, in the range d = 5-10 nm, were prepared by precipitation of TiCl₄ in aqueous medium at different pH between 2 ≤ pH ≤ 6. The influence of the nature of the acid and the temperature of thermohydrolysis on the morphology and crystalline structure of particles was also studied.

Original language	English
Title of host publication	Chemical Solution Deposition of Semiconducting and Non-Metallic Films - Proceedings of the International Symposium
Pages	195-203
Number of pages	9
Publication status	Published - 20 Jul 2006
Externally published	Yes
Event	203rd Electrochemical Society Meeting - Paris, France Duration: 27 Apr 2003 → 2 May 2003

Publication series

Name	Proceedings - Electrochemical Society
Volume	PV 2003-32

Conference

Conference	203rd Electrochemical Society Meeting
Country/Territory	France
City	Paris
Period	27/04/03 → 2/05/03

Cite this

@inproceedings{5cb3a5788c8d47c6a2bb4787987a367a,

title = "Titanium oxide synthesis in aqueous medium",

abstract = "Nanometric particles of titania, anatase, brookite and rutile polymorphs, were synthesized by thermohydrolysis of TiCl4 in aqueous medium. The control of the medium acidity allows the control of the crystalline structure, the size and the morphology of particles. In concentrated HCl (≥ 1mol.L -1) solutions, the Cl/Ti molar ratio seems to be the key factor to determine the relative proportions of brookite and rutile as well as the particle size. Nanoparticles of anatase, in the range d = 5-10 nm, were prepared by precipitation of TiCl4 in aqueous medium at different pH between 2 ≤ pH ≤ 6. The influence of the nature of the acid and the temperature of thermohydrolysis on the morphology and crystalline structure of particles was also studied.",

author = "M. Koelsch and S. Cassaignon and Guillemoles, \{J. F.\} and Jolivet, \{J. P.\}",

year = "2006",

month = jul,

day = "20",

language = "English",

isbn = "1566774330",

series = "Proceedings - Electrochemical Society",

pages = "195--203",

booktitle = "Chemical Solution Deposition of Semiconducting and Non-Metallic Films - Proceedings of the International Symposium",

note = "203rd Electrochemical Society Meeting ; Conference date: 27-04-2003 Through 02-05-2003",

}

Titanium oxide synthesis in aqueous medium. / Koelsch, M.; Cassaignon, S.; Guillemoles, J. F. et al.
Chemical Solution Deposition of Semiconducting and Non-Metallic Films - Proceedings of the International Symposium. 2006. p. 195-203 (Proceedings - Electrochemical Society; Vol. PV 2003-32).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Titanium oxide synthesis in aqueous medium

AU - Koelsch, M.

AU - Cassaignon, S.

AU - Guillemoles, J. F.

AU - Jolivet, J. P.

PY - 2006/7/20

Y1 - 2006/7/20

N2 - Nanometric particles of titania, anatase, brookite and rutile polymorphs, were synthesized by thermohydrolysis of TiCl4 in aqueous medium. The control of the medium acidity allows the control of the crystalline structure, the size and the morphology of particles. In concentrated HCl (≥ 1mol.L -1) solutions, the Cl/Ti molar ratio seems to be the key factor to determine the relative proportions of brookite and rutile as well as the particle size. Nanoparticles of anatase, in the range d = 5-10 nm, were prepared by precipitation of TiCl4 in aqueous medium at different pH between 2 ≤ pH ≤ 6. The influence of the nature of the acid and the temperature of thermohydrolysis on the morphology and crystalline structure of particles was also studied.

AB - Nanometric particles of titania, anatase, brookite and rutile polymorphs, were synthesized by thermohydrolysis of TiCl4 in aqueous medium. The control of the medium acidity allows the control of the crystalline structure, the size and the morphology of particles. In concentrated HCl (≥ 1mol.L -1) solutions, the Cl/Ti molar ratio seems to be the key factor to determine the relative proportions of brookite and rutile as well as the particle size. Nanoparticles of anatase, in the range d = 5-10 nm, were prepared by precipitation of TiCl4 in aqueous medium at different pH between 2 ≤ pH ≤ 6. The influence of the nature of the acid and the temperature of thermohydrolysis on the morphology and crystalline structure of particles was also studied.

UR - https://www.scopus.com/pages/publications/33745960044

M3 - Conference contribution

AN - SCOPUS:33745960044

SN - 1566774330

SN - 9781566774338

T3 - Proceedings - Electrochemical Society

SP - 195

EP - 203

BT - Chemical Solution Deposition of Semiconducting and Non-Metallic Films - Proceedings of the International Symposium

T2 - 203rd Electrochemical Society Meeting

Y2 - 27 April 2003 through 2 May 2003

ER -

Titanium oxide synthesis in aqueous medium

Abstract

Publication series

Conference

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