Transition Metal-Catalyzed Electroreductive Cross-Couplings for C−C Bond Formation

Meng Yu Gao; Corinne Gosmini

doi:10.1002/ijch.202300074

Transition Metal-Catalyzed Electroreductive Cross-Couplings for C−C Bond Formation

Meng Yu Gao, Corinne Gosmini

CNRS

Research output: Contribution to journal › Review article › peer-review

Abstract

This mini review provides an overview of a range of Ni-, Co- and Pd-catalyzed electroreductive cross-coupling reactions. The combination of homogeneous transition-metal catalysis and electrochemistry are green alternatives to traditional reductive cross-coupling reactions to form Csp²-Csp², Csp²-Csp³ and some Csp³-Csp³ bonds in one step. Most of these reactions use the sacrificial anode process.

Original language	English
Article number	e202300074
Journal	Israel Journal of Chemistry
Volume	64
Issue number	1-2
DOIs	https://doi.org/10.1002/ijch.202300074
Publication status	Published - 1 Jan 2024
Externally published	Yes

Keywords

C−C bond
cobalt
cross-coupling
electroreduction
nickel

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10.1002/ijch.202300074

Cite this

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title = "Transition Metal-Catalyzed Electroreductive Cross-Couplings for C−C Bond Formation",

abstract = "This mini review provides an overview of a range of Ni-, Co- and Pd-catalyzed electroreductive cross-coupling reactions. The combination of homogeneous transition-metal catalysis and electrochemistry are green alternatives to traditional reductive cross-coupling reactions to form Csp2-Csp2, Csp2-Csp3 and some Csp3-Csp3 bonds in one step. Most of these reactions use the sacrificial anode process.",

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AU - Gosmini, Corinne

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N2 - This mini review provides an overview of a range of Ni-, Co- and Pd-catalyzed electroreductive cross-coupling reactions. The combination of homogeneous transition-metal catalysis and electrochemistry are green alternatives to traditional reductive cross-coupling reactions to form Csp2-Csp2, Csp2-Csp3 and some Csp3-Csp3 bonds in one step. Most of these reactions use the sacrificial anode process.

AB - This mini review provides an overview of a range of Ni-, Co- and Pd-catalyzed electroreductive cross-coupling reactions. The combination of homogeneous transition-metal catalysis and electrochemistry are green alternatives to traditional reductive cross-coupling reactions to form Csp2-Csp2, Csp2-Csp3 and some Csp3-Csp3 bonds in one step. Most of these reactions use the sacrificial anode process.

KW - C−C bond

KW - cobalt

KW - cross-coupling

KW - electroreduction

KW - nickel

U2 - 10.1002/ijch.202300074

DO - 10.1002/ijch.202300074

M3 - Review article

AN - SCOPUS:85168160079

SN - 0021-2148

VL - 64

JO - Israel Journal of Chemistry

JF - Israel Journal of Chemistry

IS - 1-2

M1 - e202300074

ER -

Transition Metal-Catalyzed Electroreductive Cross-Couplings for C−C Bond Formation

Abstract

Keywords

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