Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Marie Pierre Denieul; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1039/cc9960002511

Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Marie Pierre Denieul
, Béatrice Quiclet-Sire
, Samir Z. Zard

Centre national de la recherche scientifique
Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

Original language	English
Pages (from-to)	2511-2512
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/cc9960002511
Publication status	Published - 1 Jan 1996

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title = "Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones",

abstract = "Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.",

author = "Denieul, \{Marie Pierre\} and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "1996",

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doi = "10.1039/cc9960002511",

language = "English",

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journal = "Chemical Communications",

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number = "22",

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T1 - Trifluoroacetonyl radicals

T2 - A versatile approach to trifluoromethyl ketones

AU - Denieul, Marie Pierre

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

AB - Radical addition of S-trifluoroacetonyl O-neopentyl dithiocarbonate 1c across an alkene occurs smoothly in the presence of a small amount of dilauroyl peroxide as initiator to give variously functionalised trifluoromethyl ketones in good yields.

U2 - 10.1039/cc9960002511

DO - 10.1039/cc9960002511

M3 - Article

AN - SCOPUS:0002460623

SN - 1359-7345

SP - 2511

EP - 2512

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Trifluoroacetonyl radicals: A versatile approach to trifluoromethyl ketones

Abstract

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