Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives

Yann Laot; Laurent Petit; Samir Z. Zard

doi:10.1039/c0cc00533a

Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives

Yann Laot
, Laurent Petit
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen.

Original language	English
Pages (from-to)	5784-5786
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	31
DOIs	https://doi.org/10.1039/c0cc00533a
Publication status	Published - 21 Aug 2010
Externally published	Yes

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title = "Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives",

abstract = "A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen.",

author = "Yann Laot and Laurent Petit and Zard, \{Samir Z.\}",

year = "2010",

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doi = "10.1039/c0cc00533a",

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journal = "Chemical Communications",

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T1 - Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives

AU - Laot, Yann

AU - Petit, Laurent

AU - Zard, Samir Z.

PY - 2010/8/21

Y1 - 2010/8/21

N2 - A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen.

AB - A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen.

U2 - 10.1039/c0cc00533a

DO - 10.1039/c0cc00533a

M3 - Article

AN - SCOPUS:77955222040

SN - 1359-7345

VL - 46

SP - 5784

EP - 5786

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives

Abstract

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