Use of the 2,5-bis-(tert-butyl)phospholide anion as an η5- ligand: Stabilisation of η5-phospholyl complexes of ruthenium and rhodium

Duncan Carmichael; Louis Ricard; François Mathey

doi:10.1039/C39940001167

Use of the 2,5-bis-(tert-butyl)phospholide anion as an η⁵- ligand: Stabilisation of η⁵-phospholyl complexes of ruthenium and rhodium

Duncan Carmichael
, Louis Ricard
, François Mathey

CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

The 2,5-bis-(tert-butyl)phospholide anion promotes η⁵- complexation to late transition metals in cases where unhindered phospholyls may favour η¹-ligation through the phosphorus lone pair.

Original language	English
Pages (from-to)	1167-1168
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39940001167
Publication status	Published - 1 Dec 1994
Externally published	Yes

Access to Document

10.1039/C39940001167

Cite this

@article{ad11516f106a4879b9a93bb9d58fdd51,

title = "Use of the 2,5-bis-(tert-butyl)phospholide anion as an η5- ligand: Stabilisation of η5-phospholyl complexes of ruthenium and rhodium",

abstract = "The 2,5-bis-(tert-butyl)phospholide anion promotes η5- complexation to late transition metals in cases where unhindered phospholyls may favour η1-ligation through the phosphorus lone pair.",

author = "Duncan Carmichael and Louis Ricard and Fran{\c c}ois Mathey",

year = "1994",

month = dec,

day = "1",

doi = "10.1039/C39940001167",

language = "English",

pages = "1167--1168",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "10",

}

TY - JOUR

T1 - Use of the 2,5-bis-(tert-butyl)phospholide anion as an η5- ligand

T2 - Stabilisation of η5-phospholyl complexes of ruthenium and rhodium

AU - Carmichael, Duncan

AU - Ricard, Louis

AU - Mathey, François

PY - 1994/12/1

Y1 - 1994/12/1

N2 - The 2,5-bis-(tert-butyl)phospholide anion promotes η5- complexation to late transition metals in cases where unhindered phospholyls may favour η1-ligation through the phosphorus lone pair.

AB - The 2,5-bis-(tert-butyl)phospholide anion promotes η5- complexation to late transition metals in cases where unhindered phospholyls may favour η1-ligation through the phosphorus lone pair.

U2 - 10.1039/C39940001167

DO - 10.1039/C39940001167

M3 - Article

AN - SCOPUS:37049067018

SN - 0022-4936

SP - 1167

EP - 1168

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Use of the 2,5-bis-(tert-butyl)phospholide anion as an η5- ligand: Stabilisation of η5-phospholyl complexes of ruthenium and rhodium

Abstract

Access to Document

Fingerprint

Cite this

Use of the 2,5-bis-(tert-butyl)phospholide anion as an η⁵- ligand: Stabilisation of η⁵-phospholyl complexes of ruthenium and rhodium