Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

Anne Claude Dublanchet; Marie Lusinchi; Samir Z. Zard

doi:10.1016/S0040-4020(02)00526-4

Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

Anne Claude Dublanchet
, Marie Lusinchi
, Samir Z. Zard

Research output: Contribution to journal › Article › peer-review

Abstract

The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy ¹H monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker.

Original language	English
Pages (from-to)	5715-5721
Number of pages	7
Journal	Tetrahedron
Volume	58
Issue number	28
DOIs	https://doi.org/10.1016/S0040-4020(02)00526-4
Publication status	Published - 8 Jul 2002
Externally published	Yes

Keywords

Free radical addition
Solid phase synthesis
Soluble polystyrene resin
Wang resin
Xanthate

Access to Document

10.1016/S0040-4020(02)00526-4

Cite this

@article{b0bce19983e9498994ecbfd3524b932c,

title = "Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin",

abstract = "The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy 1H monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker.",

keywords = "Free radical addition, Solid phase synthesis, Soluble polystyrene resin, Wang resin, Xanthate",

author = "Dublanchet, \{Anne Claude\} and Marie Lusinchi and Zard, \{Samir Z.\}",

year = "2002",

month = jul,

day = "8",

doi = "10.1016/S0040-4020(02)00526-4",

language = "English",

volume = "58",

pages = "5715--5721",

journal = "Tetrahedron",

issn = "0040-4020",

number = "28",

}

TY - JOUR

T1 - Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

AU - Dublanchet, Anne Claude

AU - Lusinchi, Marie

AU - Zard, Samir Z.

PY - 2002/7/8

Y1 - 2002/7/8

N2 - The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy 1H monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker.

AB - The straightforward synthesis of a new soluble polymer containing a Wang type linker is described. Inter-molecular radical additions of xanthates onto olefins were performed with this new resin in comparison with a classical Wang resin. The new soluble polymer analogue of Wang resin allows easy 1H monitoring of the reactions and gives better results for the radical transfer while preserving the efficient cleavage conditions of the Wang linker.

KW - Free radical addition

KW - Solid phase synthesis

KW - Soluble polystyrene resin

KW - Wang resin

KW - Xanthate

UR - https://www.scopus.com/pages/publications/0037043176

U2 - 10.1016/S0040-4020(02)00526-4

DO - 10.1016/S0040-4020(02)00526-4

M3 - Article

AN - SCOPUS:0037043176

SN - 0040-4020

VL - 58

SP - 5715

EP - 5721

JO - Tetrahedron

JF - Tetrahedron

IS - 28

ER -

Xanthates and solid-phase chemistry. A new soluble polymer analogue of Wang resin

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this