Xanthates and vinyl esters, a remarkably powerful alliance

Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.3987/REV-18-SR(F)5

Xanthates and vinyl esters, a remarkably powerful alliance

Béatrice Quiclet-Sire
, Samir Z. Zard

CNRS UMR 7652
Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.

Original language	English
Pages (from-to)	742-765
Number of pages	24
Journal	Heterocycles
Volume	99
Issue number	2
DOIs	https://doi.org/10.3987/REV-18-SR(F)5
Publication status	Published - 1 Jan 2019
Externally published	Yes

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title = "Xanthates and vinyl esters, a remarkably powerful alliance",

abstract = "The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.",

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AU - Zard, Samir Z.

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N2 - The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.

AB - The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.

U2 - 10.3987/REV-18-SR(F)5

DO - 10.3987/REV-18-SR(F)5

M3 - Article

AN - SCOPUS:85069689762

SN - 0385-5414

VL - 99

SP - 742

EP - 765

JO - Heterocycles

JF - Heterocycles

IS - 2

ER -

Xanthates and vinyl esters, a remarkably powerful alliance

Abstract

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