TY - JOUR
T1 - Xanthates and vinyl esters, a remarkably powerful alliance
AU - Quiclet-Sire, Béatrice
AU - Zard, Samir Z.
N1 - Publisher Copyright:
© 2019 The Japan Institute of Heterocyclic Chemistry.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.
AB - The present brief overview highlights and discusses the synthetic potential of the degenerative radical addition of xanthates to vinyl esters. The process results in the formation of masked aldehydes bearing numerous functionalities. It allows expedient and convergent syntheses of various structures, including cyclic and open-chain enones, trifluoromethyl enones, dienes, pyrroles, dithietanones, thiophenes, hydroxytetralones, naphthalenes and naphthols.
U2 - 10.3987/REV-18-SR(F)5
DO - 10.3987/REV-18-SR(F)5
M3 - Article
AN - SCOPUS:85069689762
SN - 0385-5414
VL - 99
SP - 742
EP - 765
JO - Heterocycles
JF - Heterocycles
IS - 2
ER -