Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.

Judith Forbes; Samir Z. Zard

doi:10.1016/S0040-4020(01)88043-1

Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.

Judith Forbes, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving β-scission of the intermediate alkoxythiocarbonyl radical.

Original language	English
Pages (from-to)	8257-8266
Number of pages	10
Journal	Tetrahedron
Volume	49
Issue number	36
DOIs	https://doi.org/10.1016/S0040-4020(01)88043-1
Publication status	Published - 3 Sept 1993
Externally published	Yes

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@article{8a0fcda5ab7741fe9fce42a879814676,

title = "Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.",

abstract = "Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving β-scission of the intermediate alkoxythiocarbonyl radical.",

author = "Judith Forbes and Zard, \{Samir Z.\}",

year = "1993",

month = sep,

day = "3",

doi = "10.1016/S0040-4020(01)88043-1",

language = "English",

volume = "49",

pages = "8257--8266",

journal = "Tetrahedron",

issn = "0040-4020",

number = "36",

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T1 - Xanthic anhydrides

T2 - A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.

AU - Forbes, Judith

AU - Zard, Samir Z.

PY - 1993/9/3

Y1 - 1993/9/3

N2 - Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving β-scission of the intermediate alkoxythiocarbonyl radical.

AB - Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving β-scission of the intermediate alkoxythiocarbonyl radical.

U2 - 10.1016/S0040-4020(01)88043-1

DO - 10.1016/S0040-4020(01)88043-1

M3 - Article

AN - SCOPUS:0027296267

SN - 0040-4020

VL - 49

SP - 8257

EP - 8266

JO - Tetrahedron

JF - Tetrahedron

IS - 36

ER -

Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.

Abstract

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